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Nitrogen reduction and functionalization by a multimetallic uranium nitride complex

Author

Listed:
  • Marta Falcone

    (Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL))

  • Lucile Chatelain

    (Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL))

  • Rosario Scopelliti

    (Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL))

  • Ivica Živković

    (Laboratory for Quantum Magnetism, Institute of Physics, École Polytechnique Fédérale de Lausanne (EPFL))

  • Marinella Mazzanti

    (Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL))

Abstract

A complex containing two uranium ions and three potassium ions, held together by a nitride group and a flexible molecular framework, can reduce and functionalize N2 under mild conditions.

Suggested Citation

  • Marta Falcone & Lucile Chatelain & Rosario Scopelliti & Ivica Živković & Marinella Mazzanti, 2017. "Nitrogen reduction and functionalization by a multimetallic uranium nitride complex," Nature, Nature, vol. 547(7663), pages 332-335, July.
    • Handle: RePEc:nat:nature:v:547:y:2017:i:7663:d:10.1038_nature23279
    DOI: 10.1038/nature23279
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    Cited by:

    1. Alyssa N. Gaiser & Cristian Celis-Barros & Frankie D. White & Maria J. Beltran-Leiva & Joseph M. Sperling & Sahan R. Salpage & Todd N. Poe & Daniela Gomez Martinez & Tian Jian & Nikki J. Wolford & Nat, 2021. "Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    2. Xiaoqing Xin & Iskander Douair & Thayalan Rajeshkumar & Yue Zhao & Shuao Wang & Laurent Maron & Congqing Zhu, 2022. "Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Liyan Cai & Bing Xu & Juanjuan Cheng & Fei Cong & Sebastian Riedel & Xuefeng Wang, 2024. "N2 cleavage by silylene and formation of H2Si(μ-N)2SiH2," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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