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Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide

Author

Listed:
  • Francisco Juliá-Hernández

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology)

  • Toni Moragas

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology)

  • Josep Cornella

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology)

  • Ruben Martin

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology
    ICREA)

Abstract

A nickel catalyst that promotes carboxylation of halogenated hydrocarbons at remote aliphatic sites with carbon dioxide via tunable and controllable chain-walking is described.

Suggested Citation

  • Francisco Juliá-Hernández & Toni Moragas & Josep Cornella & Ruben Martin, 2017. "Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide," Nature, Nature, vol. 545(7652), pages 84-88, May.
  • Handle: RePEc:nat:nature:v:545:y:2017:i:7652:d:10.1038_nature22316
    DOI: 10.1038/nature22316
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    Cited by:

    1. Fan-Tao Meng & Ya-Nan Wang & Xiao-Yan Qin & Shi-Jun Li & Jing Li & Wen-Juan Hao & Shu-Jiang Tu & Yu Lan & Bo Jiang, 2022. "Azoarene activation for Schmidt-type reaction and mechanistic insights," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    2. Daning Zeng & Zihao Liu & Guoce Huang & You Wang & Shaolin Zhu, 2024. "Regio-, stereo-, and enantioselective ipso- and migratory defluorinative olefin cross-coupling to access highly functionalized monofluoroalkenes," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    3. Sergio Sanz-Navarro & Marta Mon & Antonio Doménech-Carbó & Rossella Greco & Jorge Sánchez-Quesada & Estela Espinós-Ferri & Antonio Leyva-Pérez, 2022. "Parts–per–million of ruthenium catalyze the selective chain–walking reaction of terminal alkenes," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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