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Catalytic activation of carbon–carbon bonds in cyclopentanones

Author

Listed:
  • Ying Xia

    (University of Texas at Austin
    University of Chicago)

  • Gang Lu

    (University of Pittsburgh)

  • Peng Liu

    (University of Pittsburgh)

  • Guangbin Dong

    (University of Texas at Austin
    University of Chicago)

Abstract

In the chemical industry, it is often necessary to activate carbon–carbon bonds in order to synthesize complex organic molecules, but this is challenging when starting with simple five- or six-membered carbon rings; a new method uses a rhodium pre-catalyst and an amino-pyridine co-catalyst, enabling an overall energetically favourable reaction that involves activation of carbon–carbon bonds plus activation of carbon–hydrogen bonds.

Suggested Citation

  • Ying Xia & Gang Lu & Peng Liu & Guangbin Dong, 2016. "Catalytic activation of carbon–carbon bonds in cyclopentanones," Nature, Nature, vol. 539(7630), pages 546-550, November.
    • Handle: RePEc:nat:nature:v:539:y:2016:i:7630:d:10.1038_nature19849
    DOI: 10.1038/nature19849
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    Cited by:

    1. Qingyang Zhao & Le Yu & Yao-Du Zhang & Yong-Qiang Guo & Ming Chen & Zhi-Hui Ren & Zheng-Hui Guan, 2023. "C(alkyl)–C(vinyl) bond cleavage enabled by Retro-Pallada-Diels-Alder reaction," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Dan Ye & Hong Lu & Yi He & Zhaojing Zheng & Jinghao Wu & Hao Wei, 2022. "Rapid syntheses of N-fused heterocycles via acyl-transfer in heteroaryl ketones," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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