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Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

Author

Listed:
  • Gilbert J. Choi

    (Princeton University)

  • Qilei Zhu

    (Princeton University)

  • David C. Miller

    (Princeton University)

  • Carol J. Gu

    (Princeton University)

  • Robert R. Knowles

    (Princeton University)

Abstract

Catalytic alkylation of C–H bonds is achieved via homolysis of N–H bonds of N-alkyl amides through proton-coupled electron transfer.

Suggested Citation

  • Gilbert J. Choi & Qilei Zhu & David C. Miller & Carol J. Gu & Robert R. Knowles, 2016. "Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer," Nature, Nature, vol. 539(7628), pages 268-271, November.
    • Handle: RePEc:nat:nature:v:539:y:2016:i:7628:d:10.1038_nature19811
    DOI: 10.1038/nature19811
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    Cited by:

    1. Chaodong Wang & Zhi Chen & Jie Sun & Luwei Tong & Wenjian Wang & Shengjie Song & Jianjun Li, 2024. "Sulfonamide-directed site-selective functionalization of unactivated C(sp3)−H enabled by photocatalytic sequential electron/proton transfer," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Qian Zhang & Yulong Wang & Cameron Nickle & Ziyu Zhang & Andrea Leoncini & Dong-Chen Qi & Kai Sotthewes & Alessandro Borrini & Harold J. W. Zandvliet & Enrique Barco & Damien Thompson & Christian A. N, 2024. "Molecular switching by proton-coupled electron transport drives giant negative differential resistance," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    3. Nian Li & Jinhang Li & Mingzhe Qin & Jiajun Li & Jie Han & Chengjian Zhu & Weipeng Li & Jin Xie, 2022. "Highly selective single and multiple deuteration of unactivated C(sp3)-H bonds," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    4. Qiang Wei & Yuhsuan Lee & Weiqiu Liang & Xiaolei Chen & Bo-shuai Mu & Xi-Yang Cui & Wangsuo Wu & Shuming Bai & Zhibo Liu, 2022. "Photocatalytic direct borylation of carboxylic acids," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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