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Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides

Author

Listed:
  • Craig P. Johnston

    (Merck Center for Catalysis at Princeton University)

  • Russell T. Smith

    (Merck Center for Catalysis at Princeton University)

  • Simon Allmendinger

    (Merck Center for Catalysis at Princeton University)

  • David W. C. MacMillan

    (Merck Center for Catalysis at Princeton University)

Abstract

The long-sought direct formation of a bond between two sp3-hybridized carbon atoms is achieved by the merger of photoredox and nickel catalysis using only simple carboxylic acids and alkyl halides as starting materials.

Suggested Citation

  • Craig P. Johnston & Russell T. Smith & Simon Allmendinger & David W. C. MacMillan, 2016. "Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides," Nature, Nature, vol. 536(7616), pages 322-325, August.
    • Handle: RePEc:nat:nature:v:536:y:2016:i:7616:d:10.1038_nature19056
    DOI: 10.1038/nature19056
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    Cited by:

    1. Jiawei Li & Liuqing He & Qiong Liu & Yanwei Ren & Huanfeng Jiang, 2022. "Visible light-driven efficient palladium catalyst turnover in oxidative transformations within confined frameworks," Nature Communications, Nature, vol. 13(1), pages 1-13, December.

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