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Scalable and sustainable electrochemical allylic C–H oxidation

Author

Listed:
  • Evan J. Horn

    (The Scripps Research Institute)

  • Brandon R. Rosen

    (The Scripps Research Institute)

  • Yong Chen

    (Asymchem Life Science (Tianjin), Tianjin Economic-Technological Development Zone)

  • Jiaze Tang

    (Asymchem Life Science (Tianjin), Tianjin Economic-Technological Development Zone)

  • Ke Chen

    (Chemical Development, Bristol–Myers Squibb)

  • Martin D. Eastgate

    (Chemical Development, Bristol–Myers Squibb)

  • Phil S. Baran

    (The Scripps Research Institute)

Abstract

An electrochemical C–H oxidation strategy that exhibits broad substrate scope, operational simplicity and high chemoselectivity is described; it uses inexpensive and readily available materials and represents a scalable allylic C–H oxidation that could be adopted in large-scale industrial settings without substantial environmental impact.

Suggested Citation

  • Evan J. Horn & Brandon R. Rosen & Yong Chen & Jiaze Tang & Ke Chen & Martin D. Eastgate & Phil S. Baran, 2016. "Scalable and sustainable electrochemical allylic C–H oxidation," Nature, Nature, vol. 533(7601), pages 77-81, May.
    • Handle: RePEc:nat:nature:v:533:y:2016:i:7601:d:10.1038_nature17431
    DOI: 10.1038/nature17431
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    Cited by:

    1. Kaifa Du & Enlai Gao & Chunbo Zhang & Yongsong Ma & Peilin Wang & Rui Yu & Wenmiao Li & Kaiyuan Zheng & Xinhua Cheng & Diyong Tang & Bowen Deng & Huayi Yin & Dihua Wang, 2023. "An iron-base oxygen-evolution electrode for high-temperature electrolyzers," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. Zhiwei Zhao & Ranran Zhang & Yaowen Liu & Zile Zhu & Qiuyan Wang & Youai Qiu, 2024. "Electrochemical C−H deuteration of pyridine derivatives with D2O," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    3. Qixue Qin & Liang Zhang & Jialiang Wei & Xu Qiu & Shuanghong Hao & Xiao-De An & Ning Jiao, 2024. "Direct oxygen insertion into C-C bond of styrenes with air," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    4. Pan Ran & Aoqian Qiu & Tianshu Liu & Fangyuan Wang & Bailin Tian & Beiyao Xiang & Jun Li & Yang Lv & Mengning Ding, 2024. "Universal high-efficiency electrocatalytic olefin epoxidation via a surface-confined radical promotion," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    5. Min Liu & Tian Feng & Yanwei Wang & Guangsheng Kou & Qiuyan Wang & Qian Wang & Youai Qiu, 2023. "Metal-free electrochemical dihydroxylation of unactivated alkenes," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Zhonghe Wang & Yang Tang & Songtao Liu & Liang Zhao & Huaqing Li & Cheng He & Chunying Duan, 2024. "Energy transfer-mediated multiphoton synergistic excitation for selective C(sp3)–H functionalization with coordination polymer," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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