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Extra adsorption and adsorbate superlattice formation in metal-organic frameworks

Author

Listed:
  • Hae Sung Cho

    (Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST)

  • Hexiang Deng

    (Key Laboratory of Biomedical Polymers-Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University
    The Institute for Advanced Studies, Wuhan University)

  • Keiichi Miyasaka

    (Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST)

  • Zhiyue Dong

    (Key Laboratory of Biomedical Polymers-Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University)

  • Minhyung Cho

    (Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST)

  • Alexander V. Neimark

    (Rutgers University)

  • Jeung Ku Kang

    (Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST)

  • Omar M. Yaghi

    (Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST
    University of California, and Kavli Energy NanoSciences Institute
    King Fahd University of Petroleum and Minerals)

  • Osamu Terasaki

    (Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST
    Berzelii Centre EXSELENT on Porous Materials, Stockholm University)

Abstract

Metal-organic frameworks have a porous structure that has useful applications in gas adsorption; here, small-angle X-ray scattering is used to visualize the process of adsorption as gas pressure increases, revealing that adsorbate molecules interact across pore walls in a way that allows extra adsorbate domains to be created in the framework and to form superlattices, before the adsorbate settles down into a more uniform distribution.

Suggested Citation

  • Hae Sung Cho & Hexiang Deng & Keiichi Miyasaka & Zhiyue Dong & Minhyung Cho & Alexander V. Neimark & Jeung Ku Kang & Omar M. Yaghi & Osamu Terasaki, 2015. "Extra adsorption and adsorbate superlattice formation in metal-organic frameworks," Nature, Nature, vol. 527(7579), pages 503-507, November.
    • Handle: RePEc:nat:nature:v:527:y:2015:i:7579:d:10.1038_nature15734
    DOI: 10.1038/nature15734
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