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Catalytic asymmetric umpolung reactions of imines

Author

Listed:
  • Yongwei Wu

    (Brandeis University)

  • Lin Hu

    (Brandeis University)

  • Zhe Li

    (Brandeis University)

  • Li Deng

    (Brandeis University)

Abstract

Imines conventionally act as electrophiles towards carbon nucleophiles in the synthesis of amines, but the range of amines could be much extended if the carbon atom of the imine could be rendered electron-rich to allow it to act as a nucleophile toward a carbon electrophile; such a reaction can be promoted by new phase-transfer catalysts, leading to highly efficient asymmetric reactions of imines with enals.

Suggested Citation

  • Yongwei Wu & Lin Hu & Zhe Li & Li Deng, 2015. "Catalytic asymmetric umpolung reactions of imines," Nature, Nature, vol. 523(7561), pages 445-450, July.
    • Handle: RePEc:nat:nature:v:523:y:2015:i:7561:d:10.1038_nature14617
    DOI: 10.1038/nature14617
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    Cited by:

    1. Dachang Bai & Xiuli Guo & Xinghua Wang & Wenjie Xu & Ruoshi Cheng & Donghui Wei & Yu Lan & Junbiao Chang, 2024. "Umpolung reactivity of strained C–C σ-bonds without transition-metal catalysis," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Kiefer, Katharina & Kremer, Jasper & Zeitner, Philipp & Winkler, Bastian & Wagner, Moritz & von Cossel, Moritz, 2023. "Monetizing ecosystem services of perennial wild plant mixtures for bioenergy," Ecosystem Services, Elsevier, vol. 61(C).

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