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Ligand-enabled meta-C–H activation using a transient mediator

Author

Listed:
  • Xiao-Chen Wang

    (The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA)

  • Wei Gong

    (The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA)

  • Li-Zhen Fang

    (The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA)

  • Ru-Yi Zhu

    (The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA)

  • Suhua Li

    (The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA)

  • Keary M. Engle

    (The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA)

  • Jin-Quan Yu

    (The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA)

Abstract

A combination of norbornene and pyridine-type ligand enables commonly used ortho-directing groups to direct meta-C–H activation with palladium catalysts.

Suggested Citation

  • Xiao-Chen Wang & Wei Gong & Li-Zhen Fang & Ru-Yi Zhu & Suhua Li & Keary M. Engle & Jin-Quan Yu, 2015. "Ligand-enabled meta-C–H activation using a transient mediator," Nature, Nature, vol. 519(7543), pages 334-338, March.
    • Handle: RePEc:nat:nature:v:519:y:2015:i:7543:d:10.1038_nature14214
    DOI: 10.1038/nature14214
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    Cited by:

    1. Peng-Bo Bai & Alastair Durie & Gang-Wei Wang & Igor Larrosa, 2024. "Unlocking regioselective meta-alkylation with epoxides and oxetanes via dynamic kinetic catalyst control," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Zi-An Shen & Jiami Guo & Yixin Lu, 2024. "Facile enantioselective synthesis of multi-substituted norbornanes/norbornenes using a latent synthon strategy," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Jagrit Grover & Gaurav Prakash & Nupur Goswami & Debabrata Maiti, 2022. "Traditional and sustainable approaches for the construction of C–C bonds by harnessing C–H arylation," Nature Communications, Nature, vol. 13(1), pages 1-17, December.

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