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Metal-catalysed azidation of tertiary C–H bonds suitable for late-stage functionalization

Author

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  • Ankit Sharma

    (University of California)

  • John F. Hartwig

    (University of California)

Abstract

Most currently used catalysts for the amination of C–H bonds are ill suited to the functionalization of complex molecules; here it is shown that a mild, selective, iron-catalysed azidation of tertiary C–H bonds is suitable for the amination of complex molecules containing a range of functional groups.

Suggested Citation

  • Ankit Sharma & John F. Hartwig, 2015. "Metal-catalysed azidation of tertiary C–H bonds suitable for late-stage functionalization," Nature, Nature, vol. 517(7536), pages 600-604, January.
    • Handle: RePEc:nat:nature:v:517:y:2015:i:7536:d:10.1038_nature14127
    DOI: 10.1038/nature14127
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