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High-value alcohols and higher-oxidation-state compounds by catalytic Z-selective cross-metathesis

Author

Listed:
  • Ming Joo Koh

    (Merkert Chemistry Center, Boston College)

  • R. Kashif M. Khan

    (Merkert Chemistry Center, Boston College)

  • Sebastian Torker

    (Merkert Chemistry Center, Boston College)

  • Miao Yu

    (Merkert Chemistry Center, Boston College)

  • Malte S. Mikus

    (Merkert Chemistry Center, Boston College)

  • Amir H. Hoveyda

    (Merkert Chemistry Center, Boston College)

Abstract

A ruthenium–disulfide catalyst is presented that is effective in generating compounds of medical and industrial utility (alcohols that contain a phenol, an aldehyde, or a carboxylic acid) by room-temperature, inexpensive, high-yielding cross-metathesis.

Suggested Citation

  • Ming Joo Koh & R. Kashif M. Khan & Sebastian Torker & Miao Yu & Malte S. Mikus & Amir H. Hoveyda, 2015. "High-value alcohols and higher-oxidation-state compounds by catalytic Z-selective cross-metathesis," Nature, Nature, vol. 517(7533), pages 181-186, January.
    • Handle: RePEc:nat:nature:v:517:y:2015:i:7533:d:10.1038_nature14061
    DOI: 10.1038/nature14061
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    Cited by:

    1. Yongqiang Zhang & Dongmin Fu & Ziyang Chen & Rongqi Cui & Wenlong He & Hongyao Wang & Jiajin Chen & Yufei Chen & Shi-Jun Li & Yu Lan & Chunying Duan & Yunhe Jin, 2024. "Bifunctional iron-catalyzed alkyne Z-selective hydroalkylation and tandem Z-E inversion via radical molding and flipping," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    2. Łukasz Grzesiński & Maryana Nadirova & Jannick Guschlbauer & Artur Brotons-Rufes & Albert Poater & Anna Kajetanowicz & Karol Grela, 2024. "Preserving precise choreography of bonds in Z-stereoretentive olefin metathesis by using quinoxaline-2,3-dithiolate ligand," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

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