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Catalytic enantioselective synthesis of quaternary carbon stereocentres

Author

Listed:
  • Kyle W. Quasdorf

    (1102 Natural Sciences II, University of California)

  • Larry E. Overman

    (1102 Natural Sciences II, University of California)

Abstract

Carbon atoms to which four distinct carbon substituents are attached — quaternary carbon stereocentres — are common features of molecules found in nature; in this Review, the authors discuss catalytic enantioselective reactions that have been developed during the past decade for synthesizing organic molecules containing such carbon atoms.

Suggested Citation

  • Kyle W. Quasdorf & Larry E. Overman, 2014. "Catalytic enantioselective synthesis of quaternary carbon stereocentres," Nature, Nature, vol. 516(7530), pages 181-191, December.
    • Handle: RePEc:nat:nature:v:516:y:2014:i:7530:d:10.1038_nature14007
    DOI: 10.1038/nature14007
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    Cited by:

    1. Zongbin Jia & Liang Cheng & Long Zhang & Sanzhong Luo, 2024. "Asymmetric C–H Dehydrogenative Alkenylation via a Photo-induced Chiral α‑Imino Radical Intermediate," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    2. Ming-Ming Li & Tianze Zhang & Lei Cheng & Wei-Guo Xiao & Jin-Tao Ma & Li-Jun Xiao & Qi-Lin Zhou, 2023. "Ketone α-alkylation at the more-hindered site," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    3. Jiawen Wang & Faqian He & Xiaoyu Yang, 2021. "Asymmetric construction of acyclic quaternary stereocenters via direct enantioselective additions of α-alkynyl ketones to allenamides," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    4. Po-Kai Peng & Andrew Isho & Jeremy A. May, 2024. "Regio- and enantioselective synthesis of acyclic quaternary carbons via organocatalytic addition of organoborates to (Z)-Enediketones," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    5. Wen-Biao Wu & Bing Xu & Xue-Chun Yang & Feng Wu & Heng-Xian He & Xu Zhang & Jian-Jun Feng, 2024. "Enantioselective formal (3 + 3) cycloaddition of bicyclobutanes with nitrones enabled by asymmetric Lewis acid catalysis," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    6. Dongquan Zhang & Miaomiao Li & Jiajia Li & Aijun Lin & Hequan Yao, 2021. "Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes," Nature Communications, Nature, vol. 12(1), pages 1-7, December.

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