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Merging allylic carbon–hydrogen and selective carbon–carbon bond activation

Author

Listed:
  • Ahmad Masarwa

    (The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel)

  • Dorian Didier

    (The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel)

  • Tamar Zabrodski

    (The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel)

  • Marvin Schinkel

    (Institut Für Organische und Biomolekulare Chemie, Georg-August-Universität, Göttingen, Tammannstrasse 2, 37077 Göttingen, Germany)

  • Lutz Ackermann

    (Institut Für Organische und Biomolekulare Chemie, Georg-August-Universität, Göttingen, Tammannstrasse 2, 37077 Göttingen, Germany)

  • Ilan Marek

    (The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel)

Abstract

A method of selectively activating both allylic carbon–hydrogen bonds and carbon–carbon bonds can furnish sophisticated molecular scaffolds with all-carbon quaternary stereogenic centres that can themselves be derivatized.

Suggested Citation

  • Ahmad Masarwa & Dorian Didier & Tamar Zabrodski & Marvin Schinkel & Lutz Ackermann & Ilan Marek, 2014. "Merging allylic carbon–hydrogen and selective carbon–carbon bond activation," Nature, Nature, vol. 505(7482), pages 199-203, January.
    • Handle: RePEc:nat:nature:v:505:y:2014:i:7482:d:10.1038_nature12761
    DOI: 10.1038/nature12761
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    Cited by:

    1. Sida Li & Haijun Jiao & Xing-Zhong Shu & Lipeng Wu, 2024. "Zirconium and hafnium catalyzed C–C single bond hydroboration," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Dongquan Zhang & Miaomiao Li & Jiajia Li & Aijun Lin & Hequan Yao, 2021. "Rhodium-catalyzed intermolecular enantioselective Alder–ene type reaction of cyclopentenes with silylacetylenes," Nature Communications, Nature, vol. 12(1), pages 1-7, December.

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