Author
Listed:
- Shaun D. Wong
(Stanford University, Stanford, California 94305, USA)
- Martin Srnec
(Stanford University, Stanford, California 94305, USA)
- Megan L. Matthews
(Pennsylvania State University, University Park
Present address: Department of Chemical Physiology, The Scripps Research Institute, La Jolla, California 92307, USA.)
- Lei V. Liu
(Stanford University, Stanford, California 94305, USA)
- Yeonju Kwak
(Stanford University, Stanford, California 94305, USA)
- Kiyoung Park
(Stanford University, Stanford, California 94305, USA)
- Caleb B. Bell III
(Stanford University, Stanford, California 94305, USA)
- E. Ercan Alp
(Argonne National Laboratory, APS/XFD, 431/D003, Argonne, Illinois 60439, USA)
- Jiyong Zhao
(Argonne National Laboratory, APS/XFD, 431/D003, Argonne, Illinois 60439, USA)
- Yoshitaka Yoda
(SPring-8, JASRI, Hyogo 679-5198, Japan)
- Shinji Kitao
(Research Reactor Institute, Kyoto University)
- Makoto Seto
(Research Reactor Institute, Kyoto University)
- Carsten Krebs
(Pennsylvania State University, University Park
Pennsylvania State University, University Park)
- J. Martin Bollinger
(Pennsylvania State University, University Park
Pennsylvania State University, University Park)
- Edward I. Solomon
(Stanford University, Stanford, California 94305, USA
SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA)
Abstract
Synchrotron-based nuclear resonance vibrational spectroscopy is used to characterize the reactive Fe(iv)=O intermediate of the halogenase SyrB2; the substrate directs the orientation of this intermediate, presenting specific frontier molecular orbitals that can activate the selective halogenation.
Suggested Citation
Shaun D. Wong & Martin Srnec & Megan L. Matthews & Lei V. Liu & Yeonju Kwak & Kiyoung Park & Caleb B. Bell III & E. Ercan Alp & Jiyong Zhao & Yoshitaka Yoda & Shinji Kitao & Makoto Seto & Carsten Kreb, 2013.
"Elucidation of the Fe(iv)=O intermediate in the catalytic cycle of the halogenase SyrB2,"
Nature, Nature, vol. 499(7458), pages 320-323, July.
Handle:
RePEc:nat:nature:v:499:y:2013:i:7458:d:10.1038_nature12304
DOI: 10.1038/nature12304
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