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Activation of remote meta-C–H bonds assisted by an end-on template

Author

Listed:
  • Dasheng Leow

    (The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA)

  • Gang Li

    (The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA)

  • Tian-Sheng Mei

    (The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA)

  • Jin-Quan Yu

    (The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA)

Abstract

Rapid synthesis of complex molecules via selective functionalization of unactivated carbon–hydrogen bonds is here made easier with the use of removable ‘templates’ that enable the activation of distal bonds.

Suggested Citation

  • Dasheng Leow & Gang Li & Tian-Sheng Mei & Jin-Quan Yu, 2012. "Activation of remote meta-C–H bonds assisted by an end-on template," Nature, Nature, vol. 486(7404), pages 518-522, June.
    • Handle: RePEc:nat:nature:v:486:y:2012:i:7404:d:10.1038_nature11158
    DOI: 10.1038/nature11158
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    Cited by:

    1. Sudip Maiti & Yingzi Li & Sheuli Sasmal & Srimanta Guin & Trisha Bhattacharya & Goutam Kumar Lahiri & Robert S. Paton & Debabrata Maiti, 2022. "Expanding chemical space by para-C−H arylation of arenes," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Saikat Guria & Mirja Md Mahamudul Hassan & Jiawei Ma & Sayan Dey & Yong Liang & Buddhadeb Chattopadhyay, 2023. "A tautomerized ligand enabled meta selective C–H borylation of phenol," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Longlong Xi & Minyan Wang & Yong Liang & Yue Zhao & Zhuangzhi Shi, 2023. "Tunably strained metallacycles enable modular differentiation of aza-arene C–H bonds," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    4. Bishal Dutta & Mayank Mahajan & Animesh Ghosh & Maciej Dajek & Rafal Kowalczyk & Bhaskar Mondal & Haibo Ge & Debabrata Maiti, 2024. "Hydrogen bonding template enables remote meta-C–H alkenylation of nitroarenes with electron-deficient alkenes," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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