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Force-induced activation of covalent bonds in mechanoresponsive polymeric materials

Author

Listed:
  • Douglas A. Davis

    (Department of Chemistry,)

  • Andrew Hamilton

    (Department of Mechanical Science and Engineering,)

  • Jinglei Yang

    (The Beckman Institute,
    Present addresses: School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore (J.Y.); Department of Chemistry, Stanford University, Stanford, California, USA (T.J.M.).)

  • Lee D. Cremar

    (Department of Chemistry,)

  • Dara Van Gough

    (Department of Materials Science and Engineering,)

  • Stephanie L. Potisek

    (Department of Chemistry,)

  • Mitchell T. Ong

    (Department of Chemistry,)

  • Paul V. Braun

    (Department of Chemistry,
    The Beckman Institute,
    Department of Materials Science and Engineering,)

  • Todd J. Martínez

    (Department of Chemistry,
    The Beckman Institute,
    Present addresses: School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore (J.Y.); Department of Chemistry, Stanford University, Stanford, California, USA (T.J.M.).)

  • Scott R. White

    (The Beckman Institute,
    University of Illinois at Urbana-Champaign, Illinois 61801, USA)

  • Jeffrey S. Moore

    (Department of Chemistry,
    The Beckman Institute,
    Department of Materials Science and Engineering,)

  • Nancy R. Sottos

    (The Beckman Institute,
    Department of Materials Science and Engineering,)

Abstract

Force-responsive polymers Biology is replete with materials systems that actively and functionally respond to mechanical stimuli and thereby enable physiological processes such as the sense of touch, hearing or the growth of tissue and bone. In contrast, exposing polymers to large stresses tends to result in covalent bond rupture and hence damage or failure. Davis et al. now demonstrate that synthetic materials can be rationally designed to ensure that mechanical stress alters their properties in a useful manner. This is realized by incorporating a chemical group that responds to mechanical stress by changing its colour to red as it undergoes a ring-opening reaction, enabling the team to directly monitor the accumulation of plastic deformation. The principles underpinning this work should enable the development of other force-responsive chemical groups that could impart synthetic materials with desirable functionalities ranging from damage sensing to fully regenerative self-healing.

Suggested Citation

  • Douglas A. Davis & Andrew Hamilton & Jinglei Yang & Lee D. Cremar & Dara Van Gough & Stephanie L. Potisek & Mitchell T. Ong & Paul V. Braun & Todd J. Martínez & Scott R. White & Jeffrey S. Moore & Nan, 2009. "Force-induced activation of covalent bonds in mechanoresponsive polymeric materials," Nature, Nature, vol. 459(7243), pages 68-72, May.
    • Handle: RePEc:nat:nature:v:459:y:2009:i:7243:d:10.1038_nature07970
    DOI: 10.1038/nature07970
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    Cited by:

    1. Kaikai Zheng & Yifan Zhang & Bo Li & Steve Granick, 2023. "Phosphorescent extensophores expose elastic nonuniformity in polymer networks," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    2. Qifeng Mu & Kunpeng Cui & Zhi Jian Wang & Takahiro Matsuda & Wei Cui & Hinako Kato & Shotaro Namiki & Tomoko Yamazaki & Martin Frauenlob & Takayuki Nonoyama & Masumi Tsuda & Shinya Tanaka & Tasuku Nak, 2022. "Force-triggered rapid microstructure growth on hydrogel surface for on-demand functions," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Liu, Jiaxun & Yang, Xiuchao & Liu, Jianguo & Jiang, Xiumin, 2024. "Microscopic pyrolysis mechanisms of superfine pulverized coal based on TG-FTIR-MS and ReaxFF MD study," Energy, Elsevier, vol. 289(C).
    4. He, Yayue & Li, Wei & Han, Na & Wang, Jianping & Zhang, Xingxiang, 2019. "Facile flexible reversible thermochromic membranes based on micro/nanoencapsulated phase change materials for wearable temperature sensor," Applied Energy, Elsevier, vol. 247(C), pages 615-629.
    5. Yun Fan & Yu Shen & Jia Zhang & Xinglong Zhang & Zeqi Zhang & Hongfeng Li & Yong Peng & Jiena Weng & Ruijie Xie & Wenlei Zhang & Yu Han & Yawen Xiao & Suoying Zhang & Bing Zheng & Hao-Li Zhang & Sheng, 2024. "Wedging crystals to fabricate crystalline framework nanosheets via mechanochemistry," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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