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Battery materials for ultrafast charging and discharging

Author

Listed:
  • Byoungwoo Kang

    (Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, USA)

  • Gerbrand Ceder

    (Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, USA)

Abstract

High-speed batteries Batteries are thought of as having high energy density but low power rates, while for fast-discharging supercapacitors the opposite is true. Byoungwoo Kang and Gerbrand Ceder have now developed a lithium-ion battery that challenges that assumption, discharging extremely rapidly and maintaining a power density similar to a supercapacitor, two orders of magnitude higher than a normal lithium-ion battery. This is achieved by modifying LiFePO4, a material widely used in batteries. The starting point is nanosized LiFePO4, which already gives relatively fast discharge rates, which is then coated with a similar compound that is slightly Fe,P,O-deficient. On heating, the coating forms a glassy top layer that enhances lithium-ion mobility. The performance of batteries based on this technology could lead to new applications for electrochemical energy storage.

Suggested Citation

  • Byoungwoo Kang & Gerbrand Ceder, 2009. "Battery materials for ultrafast charging and discharging," Nature, Nature, vol. 458(7235), pages 190-193, March.
    • Handle: RePEc:nat:nature:v:458:y:2009:i:7235:d:10.1038_nature07853
    DOI: 10.1038/nature07853
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    17. Bruce Tonn & Paul Frymier & Jared Graves & Jessa Meyers, 2010. "A Sustainable Energy Scenario for the United States: Year 2050," Sustainability, MDPI, vol. 2(12), pages 1-31, November.
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    19. Xu, Jun & Liu, Binghe & Wang, Xinyi & Hu, Dayong, 2016. "Computational model of 18650 lithium-ion battery with coupled strain rate and SOC dependencies," Applied Energy, Elsevier, vol. 172(C), pages 180-189.
    20. Adams, Stefan, 2012. "Ultrafast lithium migration in surface modified LiFePO4 by heterogeneous doping," Applied Energy, Elsevier, vol. 90(1), pages 323-328.
    21. Freier, Daria & Ramirez-Iniguez, Roberto & Jafry, Tahseen & Muhammad-Sukki, Firdaus & Gamio, Carlos, 2018. "A review of optical concentrators for portable solar photovoltaic systems for developing countries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 957-968.
    22. Alan Ransil & Angela M. Belcher, 2021. "Structural ceramic batteries using an earth-abundant inorganic waterglass binder," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    23. Ecer, Fatih, 2021. "A consolidated MCDM framework for performance assessment of battery electric vehicles based on ranking strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    24. Tong Li & Tang Liu & Jian Peng & Feng Lin & Wenzheng Xu, 2018. "Charge critical sensors first: Minimize data loss in wireless rechargeable sensor networks," International Journal of Distributed Sensor Networks, , vol. 14(7), pages 15501477187, July.
    25. Bai, Hongwei & Liu, Zhaoyang & Sun, Darren Delai & Chan, Siew Hwa, 2014. "Hierarchical 3D micro-/nano-V2O5 (vanadium pentoxide) spheres as cathode materials for high-energy and high-power lithium ion-batteries," Energy, Elsevier, vol. 76(C), pages 607-613.

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