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Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs

Author

Listed:
  • Bo Wang

    (Center for Reticular Chemistry, University of California-Los Angeles, 607 East Charles E. Young Drive, Los Angeles, California 90095, USA)

  • Adrien P. Côté

    (Center for Reticular Chemistry, University of California-Los Angeles, 607 East Charles E. Young Drive, Los Angeles, California 90095, USA)

  • Hiroyasu Furukawa

    (Center for Reticular Chemistry, University of California-Los Angeles, 607 East Charles E. Young Drive, Los Angeles, California 90095, USA)

  • Michael O’Keeffe

    (Arizona State University, Tempe, Arizona 85287, USA)

  • Omar M. Yaghi

    (Center for Reticular Chemistry, University of California-Los Angeles, 607 East Charles E. Young Drive, Los Angeles, California 90095, USA)

Abstract

Get cagey with the CO2 Zeolitic imidazolate frameworks, or ZIFs, are porous crystalline materials in which organic imidazolate links connect to transition metals to form a tetrahedral framework. Many different ZIF structures can be created by simply adjusting the link–link interactions. Wang et al. used this tactic to produce two new materials with structures of a scale and complexity rarely seen before. The resulting cages contain up to 264 vertices within the pore network, and are constructed from as many as 7,524 atoms. The cages can selectively capture and store carbon dioxide with high efficiency and this, combined with stability and ease of fabrication, makes giant ZIFs promising candidates for technologies aimed at reducing carbon dioxide emissions.

Suggested Citation

  • Bo Wang & Adrien P. Côté & Hiroyasu Furukawa & Michael O’Keeffe & Omar M. Yaghi, 2008. "Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs," Nature, Nature, vol. 453(7192), pages 207-211, May.
    • Handle: RePEc:nat:nature:v:453:y:2008:i:7192:d:10.1038_nature06900
    DOI: 10.1038/nature06900
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    Cited by:

    1. Wei Zhang & Yanchen Liu & Henrik S. Jeppesen & Nicola Pinna, 2024. "Stöber method to amorphous metal-organic frameworks and coordination polymers," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Li, Lirong & Jung, Han Sol & Lee, Jae Won & Kang, Yong Tae, 2022. "Review on applications of metal–organic frameworks for CO2 capture and the performance enhancement mechanisms," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    3. Chen, Shiyi & Xiang, Wenguo & Wang, Dong & Xue, Zhipeng, 2012. "Incorporating IGCC and CaO sorption-enhanced process for power generation with CO2 capture," Applied Energy, Elsevier, vol. 95(C), pages 285-294.
    4. Li, Bingyun & Duan, Yuhua & Luebke, David & Morreale, Bryan, 2013. "Advances in CO2 capture technology: A patent review," Applied Energy, Elsevier, vol. 102(C), pages 1439-1447.
    5. Zhao, Guoying & Aziz, Baroz & Hedin, Niklas, 2010. "Carbon dioxide adsorption on mesoporous silica surfaces containing amine-like motifs," Applied Energy, Elsevier, vol. 87(9), pages 2907-2913, September.

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