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Chemical reduction of three-dimensional silica micro-assemblies into microporous silicon replicas

Author

Listed:
  • Zhihao Bao

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Michael R. Weatherspoon

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Samuel Shian

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Ye Cai

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Phillip D. Graham

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Shawn M. Allan

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Gul Ahmad

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Matthew B. Dickerson

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Benjamin C. Church

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Zhitao Kang

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Harry W. Abernathy III

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Christopher J. Summers

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Meilin Liu

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

  • Kenneth H. Sandhage

    (School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA)

Abstract

Silicon in good shape A low-temperature method of reducing silica (SiO2) to silicon (Si) could open up a multitude of new applications for micro-scale structures previously available only as the insulating oxide, such as diatom microshells and self-assembled structures made to order. The method converts silica to silicon at 650 °C — compared with the 2,000 °C or so needed for approaches involving molten silicon — at the same time retaining the original silica architecture. Silicon replicas, like the 14 µm-long example pictured, could find applications as sensors, and in the worlds of electronics, optics and biomedicine.

Suggested Citation

  • Zhihao Bao & Michael R. Weatherspoon & Samuel Shian & Ye Cai & Phillip D. Graham & Shawn M. Allan & Gul Ahmad & Matthew B. Dickerson & Benjamin C. Church & Zhitao Kang & Harry W. Abernathy III & Chris, 2007. "Chemical reduction of three-dimensional silica micro-assemblies into microporous silicon replicas," Nature, Nature, vol. 446(7132), pages 172-175, March.
  • Handle: RePEc:nat:nature:v:446:y:2007:i:7132:d:10.1038_nature05570
    DOI: 10.1038/nature05570
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    Cited by:

    1. Shen, Yafei, 2017. "Rice husk silica derived nanomaterials for sustainable applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 453-466.

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