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Exploration of molecular dynamics during transient sorption of fluids in mesoporous materials

Author

Listed:
  • Rustem Valiullin

    (Universität Leipzig)

  • Sergej Naumov

    (Universität Leipzig)

  • Petrik Galvosas

    (Universität Leipzig)

  • Jörg Kärger

    (Universität Leipzig)

  • Hyung-June Woo

    (University of Nevada)

  • Fabien Porcheron

    (University of Massachusetts)

  • Peter A. Monson

    (University of Massachusetts)

Abstract

A combination of nuclear magnetic resonance measurements and computer simulations is used to probe directly the dynamics of molecular uptake, both inside and out of the hysteresis regime, and identifies marked differences in the dynamics that are directly correlated with the existence or otherwise of hysteresis.

Suggested Citation

  • Rustem Valiullin & Sergej Naumov & Petrik Galvosas & Jörg Kärger & Hyung-June Woo & Fabien Porcheron & Peter A. Monson, 2006. "Exploration of molecular dynamics during transient sorption of fluids in mesoporous materials," Nature, Nature, vol. 443(7114), pages 965-968, October.
  • Handle: RePEc:nat:nature:v:443:y:2006:i:7114:d:10.1038_nature05183
    DOI: 10.1038/nature05183
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    Cited by:

    1. Francesco Walenszus & Volodymyr Bon & Jack D. Evans & Simon Krause & Jürgen Getzschmann & Stefan Kaskel & Muslim Dvoyashkin, 2023. "On the role of history-dependent adsorbate distribution and metastable states in switchable mesoporous metal-organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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