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Amorphous silica-like carbon dioxide

Author

Listed:
  • Mario Santoro

    (LENS, European Laboratory for Non-linear Spectroscopy and INFM
    CRS-SOFT-INFM-CNR, c/o Università di Roma “La Sapienza”)

  • Federico A. Gorelli

    (LENS, European Laboratory for Non-linear Spectroscopy and INFM
    CRS-SOFT-INFM-CNR, c/o Università di Roma “La Sapienza”)

  • Roberto Bini

    (LENS, European Laboratory for Non-linear Spectroscopy and INFM
    Dipartimento di Chimica dell'Università di Firenze)

  • Giancarlo Ruocco

    (CRS-SOFT-INFM-CNR, c/o Università di Roma “La Sapienza”
    Università di Roma “La Sapienza”)

  • Sandro Scandolo

    (The Abdus Salam International Centre for Theoretical Physics (ICTP) and INFM/Democritos National Simulation Center)

  • Wilson A. Crichton

    (European Synchrotron Research Facility)

Abstract

A new form of CO2 High pressure modifies the interatomic and intermolecular interactions in condensed matter, profoundly altering the physical and chemical properties of materials. This is dramatically demonstrated in a newly discovered form of carbon dioxide, dubbed a-carbonia. This nonmolecular amorphous carbon dioxide is a high pressure modification of the CO2 molecular solid. It is a glassy material, homologous to amorphous silica (SiO2) and germania (GeO2). The discovery could initiate new research areas in the solid-state chemistry of light elements.

Suggested Citation

  • Mario Santoro & Federico A. Gorelli & Roberto Bini & Giancarlo Ruocco & Sandro Scandolo & Wilson A. Crichton, 2006. "Amorphous silica-like carbon dioxide," Nature, Nature, vol. 441(7095), pages 857-860, June.
  • Handle: RePEc:nat:nature:v:441:y:2006:i:7095:d:10.1038_nature04879
    DOI: 10.1038/nature04879
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    Cited by:

    1. Dominique Laniel & Florian Trybel & Andrey Aslandukov & James Spender & Umbertoluca Ranieri & Timofey Fedotenko & Konstantin Glazyrin & Eleanor Lawrence Bright & Stella Chariton & Vitali B. Prakapenka, 2023. "Structure determination of ζ-N2 from single-crystal X-ray diffraction and theoretical suggestion for the formation of amorphous nitrogen," Nature Communications, Nature, vol. 14(1), pages 1-8, December.

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