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Vanadium partitioning and the oxidation state of Archaean komatiite magmas

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  • Dante Canil

    (School of Earth and Ocean Sciences, University of Victoria)

Abstract

The MgO content of komatiite lavas is an important measure of their formation temperature deep in the Archaean mantle, and forms the basis for models of the early Earth's thermal and chemical evolution1,2,3,4,5. Estimates of the primary MgO content of komatiites are sensitive to the oxidation state—characterized by the oxygen fugacity ( f O 2 )—assumed for the magmas during their crystallization. Despite two decades of study, however, f O 2 is still poorly constrained for these lavas. Here I present an estimate of the f O 2 for komatiite flows, based on the systematics of vanadium partitioning between komatiitic liquid and olivine in six well-characterized komatiite flows of varying ages. This approach shows that the oxidation state of several of these Archaean lava flows was the same as, or possibly more oxidizing than, that of present-day oceanic basalts. These results may require a downward revision of the mantle melting temperature estimated for many komatiites by about 50 °C, and suggest that the mantle was unlikely to be much less oxidized during the Archaean era than at present.

Suggested Citation

  • Dante Canil, 1997. "Vanadium partitioning and the oxidation state of Archaean komatiite magmas," Nature, Nature, vol. 389(6653), pages 842-845, October.
    • Handle: RePEc:nat:nature:v:389:y:1997:i:6653:d:10.1038_39860
    DOI: 10.1038/39860
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    Cited by:

    1. Nicholas Dygert & Gokce K. Ustunisik & Roger L. Nielsen, 2024. "Europium in plagioclase-hosted melt inclusions reveals mantle melting modulates oxygen fugacity," Nature Communications, Nature, vol. 15(1), pages 1-16, December.
    2. Huijuan Zhang & Wei Yang & Di Zhang & Hengci Tian & Renhao Ruan & Sen Hu & Yi Chen & Hejiu Hui & Yanhao Lin & Ross N. Mitchell & Di Zhang & Shitou Wu & Lihui Jia & Lixin Gu & Yangting Lin & XianHua Li, 2024. "Long-term reduced lunar mantle revealed by Chang’e-5 basalt," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    3. Fangyi Zhang & Vincenzo Stagno & Lipeng Zhang & Chen Chen & Haiyang Liu & Congying Li & Weidong Sun, 2024. "The constant oxidation state of Earth’s mantle since the Hadean," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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