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Quadruple the rate capability of high-energy batteries through a porous current collector design

Author

Listed:
  • Yusheng Ye

    (Stanford University)

  • Rong Xu

    (Stanford University)

  • Wenxiao Huang

    (Stanford University)

  • Huayue Ai

    (Stanford University)

  • Wenbo Zhang

    (Stanford University)

  • Jordan Otto Affeld

    (Stanford University)

  • Andy Cui

    (Stanford University)

  • Fang Liu

    (Stanford University)

  • Xin Gao

    (Stanford University)

  • Zhouyi Chen

    (Stanford University)

  • Tony Li

    (Stanford University)

  • Xin Xiao

    (Stanford University)

  • Zewen Zhang

    (Stanford University)

  • Yucan Peng

    (Stanford University)

  • Rafael A. Vila

    (Stanford University)

  • Yecun Wu

    (Stanford University)

  • Solomon T. Oyakhire

    (Stanford University)

  • Hideaki Kuwajima

    (Murata Manufacturing Co., Ltd, Nagaokakyo-shi)

  • Yoshiaki Suzuki

    (Murata Manufacturing Co., Ltd, Nagaokakyo-shi)

  • Ryuhei Matsumoto

    (Murata Manufacturing Co., Ltd, Nagaokakyo-shi)

  • Yasuyuki Masuda

    (Murata Manufacturing Co., Ltd, Nagaokakyo-shi)

  • Takahiro Yuuki

    (Murata Manufacturing Co., Ltd, Nagaokakyo-shi)

  • Yuri Nakayama

    (Murata Manufacturing Co., Ltd, Nagaokakyo-shi)

  • Yi Cui

    (Stanford University
    Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory)

Abstract

Achieving extremely fast charging yet maintaining high energy density remains a challenge in the battery field. Traditional current collectors, being impermeable to electrolytes, hinder the movement of Li+ ions and restrict the high-rate capability of thick electrodes. Here we conceptualize a porous current collector for energy-dense and extremely fast-charging batteries. This porous design allows Li+ ions to pass through both the current collector and the separator simultaneously, thereby reducing the effective Li+ transport distance by half and quadrupling the diffusion-limited C-rate capability without compromising the energy density. Multilayer pouch cells equipped with this current collector demonstrate high specific energy (276 Wh kg−1) and remarkable fast-charging capabilities at rates of 4 C (78.3% state of charge), 6 C (70.5% state of charge) and 10 C (54.3% state of charge). This porous current collector design is compatible with existing battery manufacturing processes and other fast-charging strategies, enriching battery configurations for designing next-generation batteries.

Suggested Citation

  • Yusheng Ye & Rong Xu & Wenxiao Huang & Huayue Ai & Wenbo Zhang & Jordan Otto Affeld & Andy Cui & Fang Liu & Xin Gao & Zhouyi Chen & Tony Li & Xin Xiao & Zewen Zhang & Yucan Peng & Rafael A. Vila & Yec, 2024. "Quadruple the rate capability of high-energy batteries through a porous current collector design," Nature Energy, Nature, vol. 9(6), pages 643-653, June.
  • Handle: RePEc:nat:natene:v:9:y:2024:i:6:d:10.1038_s41560-024-01473-2
    DOI: 10.1038/s41560-024-01473-2
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