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Inorganic glass electrolytes with polymer-like viscoelasticity

Author

Listed:
  • Tao Dai

    (Chinese Academy of Sciences)

  • Siyuan Wu

    (Chinese Academy of Sciences)

  • Yaxiang Lu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    Chinese Academy of Sciences
    Yangtze River Delta Physics Research Center Co. Ltd.)

  • Yang Yang

    (Chinese Academy of Sciences)

  • Yuan Liu

    (Chinese Academy of Sciences)

  • Chao Chang

    (Chinese Academy of Sciences)

  • Xiaohui Rong

    (Chinese Academy of Sciences
    Chinese Academy of Sciences)

  • Ruijuan Xiao

    (Chinese Academy of Sciences)

  • Junmei Zhao

    (Chinese Academy of Sciences)

  • Yanhui Liu

    (Chinese Academy of Sciences)

  • Weihua Wang

    (Chinese Academy of Sciences)

  • Liquan Chen

    (Chinese Academy of Sciences)

  • Yong-Sheng Hu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    Chinese Academy of Sciences
    Yangtze River Delta Physics Research Center Co. Ltd.)

Abstract

Solid-state batteries offer an alternative promising power source for electric vehicles. However, the interfacial mechanical stability of inorganic electrolytes is inferior to that of organic electrolytes. A high stack pressure (several to hundreds of megapascals) is often required to maintain intimate contact with electrodes. Here we report a class of viscoelastic inorganic glass (VIGLAS) to serve as solid electrolytes by simply replacing chlorine of tetrachloroaluminates with oxygen. The VIGLAS possesses high ionic conductivity (~1 mS cm−1 at 30 °C) for both Li+ and Na+, superior chemo-mechanical compatibility with 4.3 V cathodes and the ability to enable pressure-less Li- and Na-based solid-state batteries (

Suggested Citation

  • Tao Dai & Siyuan Wu & Yaxiang Lu & Yang Yang & Yuan Liu & Chao Chang & Xiaohui Rong & Ruijuan Xiao & Junmei Zhao & Yanhui Liu & Weihua Wang & Liquan Chen & Yong-Sheng Hu, 2023. "Inorganic glass electrolytes with polymer-like viscoelasticity," Nature Energy, Nature, vol. 8(11), pages 1221-1228, November.
    • Handle: RePEc:nat:natene:v:8:y:2023:i:11:d:10.1038_s41560-023-01356-y
    DOI: 10.1038/s41560-023-01356-y
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    Cited by:

    1. Hui Pan & Lei Wang & Yu Shi & Chuanchao Sheng & Sixie Yang & Ping He & Haoshen Zhou, 2024. "A solid-state lithium-ion battery with micron-sized silicon anode operating free from external pressure," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Sunyoung Lee & Hayoung Park & Jae Young Kim & Jihoon Kim & Min-Ju Choi & Sangwook Han & Sewon Kim & Wonju Kim & Ho Won Jang & Jungwon Park & Kisuk Kang, 2024. "Unveiling crystal orientation-dependent interface property in composite cathodes for solid-state batteries by in situ microscopic probe," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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