IDEAS home Printed from https://ideas.repec.org/a/nat/natene/v6y2021i3d10.1038_s41560-020-00759-5.html
   My bibliography  Save this article

Processing thin but robust electrolytes for solid-state batteries

Author

Listed:
  • Moran Balaish

    (Massachusetts Institute of Technology)

  • Juan Carlos Gonzalez-Rosillo

    (Massachusetts Institute of Technology)

  • Kun Joong Kim

    (Massachusetts Institute of Technology)

  • Yuntong Zhu

    (Massachusetts Institute of Technology)

  • Zachary D. Hood

    (Massachusetts Institute of Technology)

  • Jennifer L. M. Rupp

    (Massachusetts Institute of Technology
    Massachusetts Institute of Technology)

Abstract

The widespread adoption of high-energy-density solid-state batteries (SSBs) requires cost-effective processing and the integration of solid electrolytes of about the same thickness as the polymer-membrane separators found in conventional lithium-ion batteries. In this Review, we critically discuss the current status of research on SSB processing as well as recent cost calculations, and compare SSB oxide electrolyte material and processing options in terms of performance parameters for thick versus thin ceramics. We identify as critical for future SSB design the need to capture the thermal processing budget and the stability of the phase of interest for oxide solid electrolytes, namely lithium phosphorus oxynitride, sodium superionic conductors, perovskites and garnets, in addition to the classic plots of Arrhenius lithium transport and the electrochemical stability window. Transitioning to SSB oxide electrolyte films with thicknesses close to the range for lithium-ion battery separators could provide ample opportunities for low-temperature ceramic manufacture and potential cost reduction.

Suggested Citation

  • Moran Balaish & Juan Carlos Gonzalez-Rosillo & Kun Joong Kim & Yuntong Zhu & Zachary D. Hood & Jennifer L. M. Rupp, 2021. "Processing thin but robust electrolytes for solid-state batteries," Nature Energy, Nature, vol. 6(3), pages 227-239, March.
    • Handle: RePEc:nat:natene:v:6:y:2021:i:3:d:10.1038_s41560-020-00759-5
    DOI: 10.1038/s41560-020-00759-5
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41560-020-00759-5
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.
    File URL: https://libkey.io/10.1038/s41560-020-00759-5?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Lei Gao & Xinyu Zhang & Jinlong Zhu & Songbai Han & Hao Zhang & Liping Wang & Ruo Zhao & Song Gao & Shuai Li & Yonggang Wang & Dubin Huang & Yusheng Zhao & Ruqiang Zou, 2023. "Boosting lithium ion conductivity of antiperovskite solid electrolyte by potassium ions substitution for cation clusters," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Sung-Kyun Jung & Hyeokjo Gwon & Hyungsub Kim & Gabin Yoon & Dongki Shin & Jihyun Hong & Changhoon Jung & Ju-Sik Kim, 2022. "Unlocking the hidden chemical space in cubic-phase garnet solid electrolyte for efficient quasi-all-solid-state lithium batteries," Nature Communications, Nature, vol. 13(1), pages 1-13, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natene:v:6:y:2021:i:3:d:10.1038_s41560-020-00759-5. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.