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Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

Author

Listed:
  • Mark V. Khenkin

    (Ben-Gurion University of the Negev
    Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, PVcomB)

  • Eugene A. Katz

    (Ben-Gurion University of the Negev
    Ben-Gurion University of the Negev)

  • Antonio Abate

    (Helmholtz-Zentrum Berlin für Materialien und Energie GmbH)

  • Giorgio Bardizza

    (European Commission, Joint Research Centre (JRC))

  • Joseph J. Berry

    (National Renewable Energy Laboratory)

  • Christoph Brabec

    (Friedrich Alexander University Erlangen Nürnberg
    Forschungszentrum Jülich (FZJ))

  • Francesca Brunetti

    (University of Rome Tor Vergata)

  • Vladimir Bulović

    (Massachusetts Institute of Technology)

  • Quinn Burlingame

    (Princeton University)

  • Aldo Di Carlo

    (University of Rome Tor Vergata)

  • Rongrong Cheacharoen

    (Chulalongkorn University)

  • Yi-Bing Cheng

    (Wuhan University of Technology)

  • Alexander Colsmann

    (Light Technology Institute, Karlsruhe Institute of Technology (KIT))

  • Stephane Cros

    (University of Grenoble Alpes, CEA, LITEN, INES)

  • Konrad Domanski

    (Fluxim AG)

  • Michał Dusza

    (Saule Technologies, Wroclaw Technology Park)

  • Christopher J. Fell

    (CSIRO Energy)

  • Stephen R. Forrest

    (University of Michigan
    University of Michigan
    University of Michigan)

  • Yulia Galagan

    (TNO - Solliance, High Tech Campus)

  • Diego Di Girolamo

    (University of Rome Tor Vergata
    University of Rome La Sapienza)

  • Michael Grätzel

    (Laboratory for Photonics and Interfaces, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne)

  • Anders Hagfeldt

    (Laboratory of Photomolecular Science, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne)

  • Elizabeth Hauff

    (Vrije Universiteit Amsterdam)

  • Harald Hoppe

    (Friedrich Schiller University Jena)

  • Jeff Kettle

    (Bangor University, Bangor)

  • Hans Köbler

    (Helmholtz-Zentrum Berlin für Materialien und Energie GmbH)

  • Marina S. Leite

    (University of Maryland
    University of California)

  • Shengzhong (Frank) Liu

    (Chinese Academy of Sciences, Dalian
    Shaanxi Normal University)

  • Yueh-Lin Loo

    (Princeton University
    Princeton University)

  • Joseph M. Luther

    (National Renewable Energy Laboratory)

  • Chang-Qi Ma

    (Printable Electronics Research Center, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences (CAS))

  • Morten Madsen

    (University of Southern Denmark)

  • Matthieu Manceau

    (University of Grenoble Alpes, CEA, LITEN, INES)

  • Muriel Matheron

    (University of Grenoble Alpes, CEA, LITEN, INES)

  • Michael McGehee

    (National Renewable Energy Laboratory
    University of Colorado Boulder)

  • Rico Meitzner

    (Friedrich Schiller University Jena)

  • Mohammad Khaja Nazeeruddin

    (Group for Molecular Engineering of Functional Materials, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne)

  • Ana Flavia Nogueira

    (University of Campinas – UNICAMP)

  • Çağla Odabaşı

    (Boğaziçi University, Bebek)

  • Anna Osherov

    (Massachusetts Institute of Technology)

  • Nam-Gyu Park

    (Sungkyunkwan University (SKKU))

  • Matthew O. Reese

    (National Renewable Energy Laboratory)

  • Francesca De Rossi

    (University of Rome Tor Vergata
    Swansea University, Bay Campus)

  • Michael Saliba

    (Technical University of Darmstadt
    IEK-5 Photovoltaik, Forschungszentrum Jülich GmbH)

  • Ulrich S. Schubert

    (Friedrich Schiller University Jena
    Friedrich Schiller University Jena)

  • Henry J. Snaith

    (University of Oxford)

  • Samuel D. Stranks

    (University of Cambridge)

  • Wolfgang Tress

    (Laboratory of Photomolecular Science, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne)

  • Pavel A. Troshin

    (Skolkovo Institute of Science and Technology
    IPCP RAS)

  • Vida Turkovic

    (University of Southern Denmark)

  • Sjoerd Veenstra

    (TNO - Solliance, High Tech Campus)

  • Iris Visoly-Fisher

    (Ben-Gurion University of the Negev
    Ben-Gurion University of the Negev)

  • Aron Walsh

    (Imperial College London
    Yonsei University)

  • Trystan Watson

    (Swansea University, Bay Campus)

  • Haibing Xie

    (CSIC and The Barcelona Institute of Science and Technology)

  • Ramazan Yıldırım

    (Boğaziçi University, Bebek)

  • Shaik Mohammed Zakeeruddin

    (Laboratory for Photonics and Interfaces, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne)

  • Kai Zhu

    (National Renewable Energy Laboratory)

  • Monica Lira-Cantu

    (CSIC and The Barcelona Institute of Science and Technology)

Abstract

Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis.

Suggested Citation

  • Mark V. Khenkin & Eugene A. Katz & Antonio Abate & Giorgio Bardizza & Joseph J. Berry & Christoph Brabec & Francesca Brunetti & Vladimir Bulović & Quinn Burlingame & Aldo Di Carlo & Rongrong Cheacharo, 2020. "Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures," Nature Energy, Nature, vol. 5(1), pages 35-49, January.
  • Handle: RePEc:nat:natene:v:5:y:2020:i:1:d:10.1038_s41560-019-0529-5
    DOI: 10.1038/s41560-019-0529-5
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    Citations

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    Cited by:

    1. Zi Shuai Wang & Yidan An & Xingang Ren & Hong Zhang & Zhanfeng Huang & Hin-Lap Yip & Zhixiang Huang & Wallace C. H. Choy, 2024. "Device deficiency and degradation diagnosis model of Perovskite solar cells through hysteresis analysis," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
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    3. Xinlong Wang & Zhiqin Ying & Jingming Zheng & Xin Li & Zhipeng Zhang & Chuanxiao Xiao & Ying Chen & Ming Wu & Zhenhai Yang & Jingsong Sun & Jia-Ru Xu & Jiang Sheng & Yuheng Zeng & Xi Yang & Guichuan X, 2023. "Long-chain anionic surfactants enabling stable perovskite/silicon tandems with greatly suppressed stress corrosion," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
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    10. Safat Dipta, Shahriyar & Schoenlaub, Jean & Habibur Rahaman, Md & Uddin, Ashraf, 2022. "Estimating the potential for semitransparent organic solar cells in agrophotovoltaic greenhouses," Applied Energy, Elsevier, vol. 328(C).
    11. Yuri Choi & Rashmi Mehrotra & Sang-Hak Lee & Trang Vu Thien Nguyen & Inhui Lee & Jiyeong Kim & Hwa-Young Yang & Hyeonmyeong Oh & Hyunwoo Kim & Jae-Won Lee & Yong Hwan Kim & Sung-Yeon Jang & Ji-Wook Ja, 2022. "Bias-free solar hydrogen production at 19.8 mA cm−2 using perovskite photocathode and lignocellulosic biomass," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    12. Zhuang Zhang & Huanhuan Wang & T. Jesper Jacobsson & Jingshan Luo, 2022. "Big data driven perovskite solar cell stability analysis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    13. Jiajia Suo & Bowen Yang & Edoardo Mosconi & Dmitry Bogachuk & Tiarnan A. S. Doherty & Kyle Frohna & Dominik J. Kubicki & Fan Fu & YeonJu Kim & Oussama Er-Raji & Tiankai Zhang & Lorenzo Baldinelli & Lu, 2024. "Multifunctional sulfonium-based treatment for perovskite solar cells with less than 1% efficiency loss over 4,500-h operational stability tests," Nature Energy, Nature, vol. 9(2), pages 172-183, February.
    14. Noor Titan Putri Hartono & Hans Köbler & Paolo Graniero & Mark Khenkin & Rutger Schlatmann & Carolin Ulbrich & Antonio Abate, 2023. "Stability follows efficiency based on the analysis of a large perovskite solar cells ageing dataset," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
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    19. Li, Bowei & Jayawardena, K.D. G. Imalka & Zhang, Jing & Bandara, Rajapakshe Mudiyanselage Indrachapa & Liu, Xueping & Bi, Jingxin & Silva, Shashini M. & Liu, Dongtao & Underwood, Cameron C.L. & Xiang,, 2024. "Stability of formamidinium tin triiodide-based inverted perovskite solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    20. Raman, Rohith Kumar & Gurusamy Thangavelu, Senthil A. & Venkataraj, Selvaraj & Krishnamoorthy, Ananthanarayanan, 2021. "Materials, methods and strategies for encapsulation of perovskite solar cells: From past to present," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    21. Mubai Li & Riming Sun & Jingxi Chang & Jingjin Dong & Qiushuang Tian & Hongze Wang & Zihao Li & Pinghui Yang & Haokun Shi & Chao Yang & Zichao Wu & Renzhi Li & Yingguo Yang & Aifei Wang & Shitong Zhan, 2023. "Orientated crystallization of FA-based perovskite via hydrogen-bonded polymer network for efficient and stable solar cells," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    22. Sara Pescetelli & Antonio Agresti & George Viskadouros & Stefano Razza & Konstantinos Rogdakis & Ioannis Kalogerakis & Emmanuel Spiliarotis & Enrico Leonardi & Paolo Mariani & Luca Sorbello & Marco Pi, 2022. "Integration of two-dimensional materials-based perovskite solar panels into a stand-alone solar farm," Nature Energy, Nature, vol. 7(7), pages 597-607, July.

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