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Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans

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  • Nengchao Luo

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Tiziano Montini

    (INSTM Research Unit, ICCOM-CNR Trieste Research Unit, University of Trieste)

  • Jian Zhang

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Paolo Fornasiero

    (INSTM Research Unit, ICCOM-CNR Trieste Research Unit, University of Trieste)

  • Emiliano Fonda

    (Saint Aubin)

  • Tingting Hou

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Wei Nie

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Jianmin Lu

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Junxue Liu

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Marc Heggen

    (Ernst Ruska Centre for Microscopy and Spectroscopy with Electrons and Peter Grünberg Institute, Forschungszentrum Juelich GmbH)

  • Long Lin

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Changtong Ma

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Min Wang

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Fengtao Fan

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Shengye Jin

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Feng Wang

    (Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

Abstract

Photocatalytic hydrogen production from biomass is a promising alternative to water splitting thanks to the oxidation half-reaction being more facile and its ability to simultaneously produce solar fuels and value-added chemicals. Here, we demonstrate the coproduction of H2 and diesel fuel precursors from lignocellulose-derived methylfurans via acceptorless dehydrogenative C−C coupling, using a Ru-doped ZnIn2S4 catalyst and driven by visible light. With this chemistry, up to 1.04 g gcatalyst−1 h−1 of diesel fuel precursors (~41% of which are precursors of branched-chain alkanes) are produced with selectivity higher than 96%, together with 6.0 mmol gcatalyst−1 h−1 of H2. Subsequent hydrodeoxygenation reactions yield the desired diesel fuels comprising straight- and branched-chain alkanes. We suggest that Ru dopants, substituted in the position of indium ions in the ZnIn2S4 matrix, improve charge separation efficiency, thereby accelerating C−H activation for the coproduction of H2 and diesel fuel precursors.

Suggested Citation

  • Nengchao Luo & Tiziano Montini & Jian Zhang & Paolo Fornasiero & Emiliano Fonda & Tingting Hou & Wei Nie & Jianmin Lu & Junxue Liu & Marc Heggen & Long Lin & Changtong Ma & Min Wang & Fengtao Fan & Sh, 2019. "Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans," Nature Energy, Nature, vol. 4(7), pages 575-584, July.
    • Handle: RePEc:nat:natene:v:4:y:2019:i:7:d:10.1038_s41560-019-0403-5
    DOI: 10.1038/s41560-019-0403-5
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    Cited by:

    1. Chen, Bi-Shuang & Zeng, Yong-Yi & Liu, Lan & Chen, Lei & Duan, Peigao & Luque, Rafael & Ge, Ran & Zhang, Wuyuan, 2022. "Advances in catalytic decarboxylation of bioderived fatty acids to diesel-range alkanes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    2. Fei Chen & Chang-Wei Bai & Pi-Jun Duan & Zhi-Quan Zhang & Yi-Jiao Sun & Xin-Jia Chen & Qi Yang & Han-Qing Yu, 2024. "Merging semi-crystallization and multispecies iodine intercalation at photo-redox interfaces for dual high-value synthesis," Nature Communications, Nature, vol. 15(1), pages 1-17, December.
    3. Wang, Zhihao & Xia, Shengpeng & Wang, Xiaobo & Fan, Yuyang & Zhao, Kun & Wang, Shuang & Zhao, Zengli & Zheng, Anqing, 2024. "Catalytic production of 5-hydroxymethylfurfural from lignocellulosic biomass: Recent advances, challenges and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 196(C).
    4. Ndayisenga, Fabrice & Yu, Zhisheng & Zheng, Jianzhong & Wang, Bobo & Liang, Hongxia & Phulpoto, Irfan Ali & Habiyakare, Telesphore & Zhou, Dandan, 2021. "Microbial electrohydrogenesis cell and dark fermentation integrated system enhances biohydrogen production from lignocellulosic agricultural wastes: Substrate pretreatment towards optimization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    5. Xiaowei Shi & Chao Dai & Xin Wang & Jiayue Hu & Junying Zhang & Lingxia Zheng & Liang Mao & Huajun Zheng & Mingshan Zhu, 2022. "Protruding Pt single-sites on hexagonal ZnIn2S4 to accelerate photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    6. Nwosu, Ugochukwu & Wang, Aiguo & Palma, Bruna & Zhao, Heng & Khan, Mohd Adnan & Kibria, Md & Hu, Jinguang, 2021. "Selective biomass photoreforming for valuable chemicals and fuels: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    7. Zhao, Wan & Chen, Zhi & Yang, Xiuru & Qian, Xiaoxiao & Liu, Chunxi & Zhou, Dantong & Sun, Tao & Zhang, Ming & Wei, Guoying & Dissanayake, Pavani Dulanja & Ok, Yong Sik, 2020. "Recent advances in photocatalytic hydrogen evolution with high-performance catalysts without precious metals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 132(C).
    8. Cruz, Pedro L. & Dufour, Javier & Iribarren, Diego, 2023. "Conceptualization and application of an environmental dashboard to benchmark technical aspects in photocatalytic hydrogen production," Renewable Energy, Elsevier, vol. 210(C), pages 424-430.

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