Planar p–n homojunction perovskite solar cells with efficiency exceeding 21.3%

Perovskite solar cells (PSCs) have emerged as an attractive photovoltaic technology thanks to their outstanding power conversion efficiency (PCE). Further improvement in the device efficiency is limited by the recombination of the charge carriers in the perovskite layer even when employing heterojunction-based architectures. Here, we propose and demonstrate a p-type perovskite/n-type perovskite homojunction whose built-in electric field promotes oriented transport of the photo-induced carriers, thus reducing carrier recombination losses. By controlling the stoichiometry of the perovskite precursors, we are able to induce n-type or p-type doping. We integrate the homojunction structure in a planar PSC combining a thermally evaporated p-type perovskite layer on a solution-processed n-type perovskite layer. The PSC with a MAPbI3 homojunction achieves a PCE of 20.80% (20.5% certified PCE), whereas the PSC based on a FA0.15MA0.85PbI3 homojunction delivers a PCE of 21.38%. We demonstrate that the homojunction structure is an effective approach, beyond existing planar heterojunction PSCs, to achieve highly efficient PSCs with reduced carrier recombination losses.