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Oriented electron transmission in polyoxometalate-metalloporphyrin organic framework for highly selective electroreduction of CO2

Author

Listed:
  • Yi-Rong Wang

    (Nanjing Normal University)

  • Qing Huang

    (Nanjing Normal University)

  • Chun-Ting He

    (Jiangxi Normal University)

  • Yifa Chen

    (Nanjing Normal University)

  • Jiang Liu

    (Nanjing Normal University)

  • Feng-Cui Shen

    (Nanjing Normal University)

  • Ya-Qian Lan

    (Nanjing Normal University)

Abstract

The design of highly stable, selective and efficient electrocatalysts for CO2 reduction reaction is desirable while largely unmet. In this work, a series of precisely designed polyoxometalate-metalloporphyrin organic frameworks are developed. Noted that the integration of {ε-PMo8VMo4VIO40Zn4} cluster and metalloporphyrin endows these polyoxometalate-metalloporphyrin organic frameworks greatly advantages in terms of electron collecting and donating, electron migration and electrocatalytic active component in the CO2 reduction reaction. Thus-obtained catalysts finally present excellent performances and the mechanisms of catalysis processes are discussed and revealed by density functional theory calculations. Most importantly, Co-PMOF exhibits remarkable faradaic efficiency ( > 94%) over a wide potential range (−0.8 to −1.0 V). Its best faradaic efficiency can reach up to 99% (highest in reported metal-organic frameworks) and it exhibits a high turnover frequency of 1656 h−1 and excellent catalysis stability ( > 36 h).

Suggested Citation

  • Yi-Rong Wang & Qing Huang & Chun-Ting He & Yifa Chen & Jiang Liu & Feng-Cui Shen & Ya-Qian Lan, 2018. "Oriented electron transmission in polyoxometalate-metalloporphyrin organic framework for highly selective electroreduction of CO2," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-06938-z
    DOI: 10.1038/s41467-018-06938-z
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    Cited by:

    1. Chengcheng Zhu & Li Xu & Yazi Liu & Jiang Liu & Jin Wang & Hanjun Sun & Ya-Qian Lan & Chen Wang, 2024. "Polyoxometalate-based plasmonic electron sponge membrane for nanofluidic osmotic energy conversion," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    2. Amir Masoud Parvanian & Nasrin Sadeghi & Ahmad Rafiee & Cameron J. Shearer & Mehdi Jafarian, 2021. "Application of Porous Materials for CO 2 Reutilization: A Review," Energies, MDPI, vol. 15(1), pages 1-65, December.
    3. Hao Sun & Ling Chen & Likun Xiong & Kun Feng & Yufeng Chen & Xiang Zhang & Xuzhou Yuan & Baiyu Yang & Zhao Deng & Yu Liu & Mark H. Rümmeli & Jun Zhong & Yan Jiao & Yang Peng, 2021. "Promoting ethylene production over a wide potential window on Cu crystallites induced and stabilized via current shock and charge delocalization," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    4. Ming-Yan Lan & Yu-Hang Li & Chong-Chen Wang & Xin-Jie Li & Jiazhen Cao & Linghui Meng & Shuai Gao & Yuhui Ma & Haodong Ji & Mingyang Xing, 2024. "Multi-channel electron transfer induced by polyvanadate in metal-organic framework for boosted peroxymonosulfate activation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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