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Metallo-polyelectrolytes as a class of ionic macromolecules for functional materials

Author

Listed:
  • Tianyu Zhu

    (University of South Carolina)

  • Ye Sha

    (University of South Carolina)

  • Jing Yan

    (Northwestern Polytechnical University)

  • Parasmani Pageni

    (University of South Carolina)

  • Md Anisur Rahman

    (University of South Carolina)

  • Yi Yan

    (Northwestern Polytechnical University)

  • Chuanbing Tang

    (University of South Carolina)

Abstract

The fields of soft polymers and macromolecular sciences have enjoyed a unique combination of metals and organic frameworks in the name of metallopolymers or organometallic polymers. When metallopolymers carry charged groups, they form a class of metal-containing polyelectrolytes or metallo-polyelectrolytes. This review identifies the unique properties and functions of metallo-polyelectrolytes compared with conventional organo-polyelectrolytes, in the hope of shedding light on the formation of functional materials with intriguing applications and potential benefits. It concludes with a critical perspective on the challenges and hurdles for metallo-polyelectrolytes, especially experimental quantitative analysis and theoretical modeling of ionic binding.

Suggested Citation

  • Tianyu Zhu & Ye Sha & Jing Yan & Parasmani Pageni & Md Anisur Rahman & Yi Yan & Chuanbing Tang, 2018. "Metallo-polyelectrolytes as a class of ionic macromolecules for functional materials," Nature Communications, Nature, vol. 9(1), pages 1-15, December.
    • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-06475-9
    DOI: 10.1038/s41467-018-06475-9
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    Cited by:

    1. Seola Lee & Pierre J. Walker & Seneca J. Velling & Amylynn Chen & Zane W. Taylor & Cyrus J.B.M Fiori & Vatsa Gandhi & Zhen-Gang Wang & Julia R. Greer, 2024. "Molecular control via dynamic bonding enables material responsiveness in additively manufactured metallo-polyelectrolytes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Sihan Tang & Jiang Gong & Yunsong Shi & Shifeng Wen & Qiang Zhao, 2022. "Spontaneous water-on-water spreading of polyelectrolyte membranes inspired by skin formation," Nature Communications, Nature, vol. 13(1), pages 1-8, December.

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