IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v9y2018i1d10.1038_s41467-018-03896-4.html
   My bibliography  Save this article

Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution

Author

Listed:
  • Yurui Xue

    (The Chinese Academy of Sciences)

  • Bolong Huang

    (The Hong Kong Polytechnic University—Hung Hom)

  • Yuanping Yi

    (The Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yuan Guo

    (The Chinese Academy of Sciences)

  • Zicheng Zuo

    (The Chinese Academy of Sciences)

  • Yongjun Li

    (The Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Zhiyu Jia

    (The Chinese Academy of Sciences)

  • Huibiao Liu

    (The Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yuliang Li

    (The Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

Abstract

Electrocatalysis by atomic catalysts is a major focus of chemical and energy conversion effort. Although transition-metal-based bulk electrocatalysts for electrochemical application on energy conversion processes have been reported frequently, anchoring the stable transition-metal atoms (e.g. nickel and iron) still remains a practical challenge. Here we report a strategy for fabrication of ACs comprising only isolated nickel/iron atoms anchored on graphdiyne. Our findings identify the very narrow size distributions of both nickel (1.23 Å) and iron (1.02 Å), typical sizes of single-atom nickel and iron. The precision of this method motivates us to develop a general approach in the field of single-atom transition-metal catalysis. Such atomic catalysts have high catalytic activity and stability for hydrogen evolution reactions.

Suggested Citation

  • Yurui Xue & Bolong Huang & Yuanping Yi & Yuan Guo & Zicheng Zuo & Yongjun Li & Zhiyu Jia & Huibiao Liu & Yuliang Li, 2018. "Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-03896-4
    DOI: 10.1038/s41467-018-03896-4
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-018-03896-4
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-018-03896-4?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Qiyou Wang & Kang Liu & Kangman Hu & Chao Cai & Huangjingwei Li & Hongmei Li & Matias Herran & Ying-Rui Lu & Ting-Shan Chan & Chao Ma & Junwei Fu & Shiguo Zhang & Ying Liang & Emiliano Cortés & Min Li, 2022. "Attenuating metal-substrate conjugation in atomically dispersed nickel catalysts for electroreduction of CO2 to CO," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Weiwei Fu & Jin Wan & Huijuan Zhang & Jian Li & Weigen Chen & Yuke Li & Zaiping Guo & Yu Wang, 2022. "Photoinduced loading of electron-rich Cu single atoms by moderate coordination for hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Yang Gao & Yurui Xue & Lu Qi & Chengyu Xing & Xuchen Zheng & Feng He & Yuliang Li, 2022. "Rhodium nanocrystals on porous graphdiyne for electrocatalytic hydrogen evolution from saline water," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    4. Zhiqiang Zheng & Lu Qi & Xiaoyu Luan & Shuya Zhao & Yurui Xue & Yuliang Li, 2024. "Growing highly ordered Pt and Mn bimetallic single atomic layers over graphdiyne," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-03896-4. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.