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Multiple-component covalent organic frameworks

Author

Listed:
  • Ning Huang

    (Field of Energy and Environment, School of Materials Science, Japan Advanced Institute of Science and Technology)

  • Lipeng Zhai

    (Field of Energy and Environment, School of Materials Science, Japan Advanced Institute of Science and Technology)

  • Damien E. Coupry

    (Scientific Computing and Modelling NV, Vrije Universiteit, Theoretical Chemistry De Boelelaan 1083)

  • Matthew A. Addicoat

    (Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig)

  • Keiko Okushita

    (Institute for Molecular Science, National Institutes of Natural Sciences)

  • Katsuyuki Nishimura

    (Institute for Molecular Science, National Institutes of Natural Sciences)

  • Thomas Heine

    (Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig)

  • Donglin Jiang

    (Field of Energy and Environment, School of Materials Science, Japan Advanced Institute of Science and Technology)

Abstract

Covalent organic frameworks are a class of crystalline porous polymers that integrate molecular building blocks into periodic structures and are usually synthesized using two-component [1+1] condensation systems comprised of one knot and one linker. Here we report a general strategy based on multiple-component [1+2] and [1+3] condensation systems that enable the use of one knot and two or three linker units for the synthesis of hexagonal and tetragonal multiple-component covalent organic frameworks. Unlike two-component systems, multiple-component covalent organic frameworks feature asymmetric tiling of organic units into anisotropic skeletons and unusually shaped pores. This strategy not only expands the structural complexity of skeletons and pores but also greatly enhances their structural diversity. This synthetic platform is also widely applicable to multiple-component electron donor–acceptor systems, which lead to electronic properties that are not simply linear summations of those of the conventional [1+1] counterparts.

Suggested Citation

  • Ning Huang & Lipeng Zhai & Damien E. Coupry & Matthew A. Addicoat & Keiko Okushita & Katsuyuki Nishimura & Thomas Heine & Donglin Jiang, 2016. "Multiple-component covalent organic frameworks," Nature Communications, Nature, vol. 7(1), pages 1-12, November.
    • Handle: RePEc:nat:natcom:v:7:y:2016:i:1:d:10.1038_ncomms12325
    DOI: 10.1038/ncomms12325
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    Cited by:

    1. Yong Liu & Liangchao Yuan & Wenwen Chi & Wang-Kang Han & Jinfang Zhang & Huan Pang & Zhongchang Wang & Zhi-Guo Gu, 2024. "Cairo pentagon tessellated covalent organic frameworks with mcm topology for near-infrared phototherapy," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Jia Yen Lai & Lock Hei Ngu & Siti Salwa Hashim, 2021. "A review of CO2 adsorbents performance for different carbon capture technology processes conditions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(5), pages 1076-1117, October.

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