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Efficient near-infrared up-conversion photoluminescence in carbon nanotubes

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  • Naoto Akizuki

    (Institute of Advanced Energy, Kyoto University)

  • Shun Aota

    (Institute of Advanced Energy, Kyoto University)

  • Shinichiro Mouri

    (Institute of Advanced Energy, Kyoto University)

  • Kazunari Matsuda

    (Institute of Advanced Energy, Kyoto University)

  • Yuhei Miyauchi

    (Institute of Advanced Energy, Kyoto University
    PRESTO, Japan Science and Technology Agency
    Graduate School of Science, Nagoya University)

Abstract

Photoluminescence phenomena normally obey Stokes’ law of luminescence according to which the emitted photon energy is typically lower than its excitation counterparts. Here we show that carbon nanotubes break this rule under one-photon excitation conditions. We found that the carbon nanotubes exhibit efficient near-infrared photoluminescence upon photoexcitation even at an energy lying >100–200 meV below that of the emission at room temperature. This apparently anomalous phenomenon is attributed to efficient one-phonon-assisted up-conversion processes resulting from unique excited-state dynamics emerging in an individual carbon nanotube with accidentally or intentionally embedded localized states. These findings may open new doors for energy harvesting, optoelectronics and deep-tissue photoluminescence imaging in the near-infrared optical range.

Suggested Citation

  • Naoto Akizuki & Shun Aota & Shinichiro Mouri & Kazunari Matsuda & Yuhei Miyauchi, 2015. "Efficient near-infrared up-conversion photoluminescence in carbon nanotubes," Nature Communications, Nature, vol. 6(1), pages 1-6, December.
  • Handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms9920
    DOI: 10.1038/ncomms9920
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