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In-operando high-speed tomography of lithium-ion batteries during thermal runaway

Author

Listed:
  • Donal P. Finegan

    (Electrochemical Innovation Lab, University College London, Torrington Place)

  • Mario Scheel

    (ESRF, The European Synchrotron
    Synchrotron Soleil, L'Orme des Merisiers)

  • James B. Robinson

    (Electrochemical Innovation Lab, University College London, Torrington Place)

  • Bernhard Tjaden

    (Electrochemical Innovation Lab, University College London, Torrington Place)

  • Ian Hunt

    (Imperial College London, South Kensington Campus)

  • Thomas J. Mason

    (Electrochemical Innovation Lab, University College London, Torrington Place)

  • Jason Millichamp

    (Electrochemical Innovation Lab, University College London, Torrington Place)

  • Marco Di Michiel

    (ESRF, The European Synchrotron)

  • Gregory J. Offer

    (Imperial College London, South Kensington Campus)

  • Gareth Hinds

    (National Physical Laboratory)

  • Dan J.L. Brett

    (Electrochemical Innovation Lab, University College London, Torrington Place)

  • Paul R. Shearing

    (Electrochemical Innovation Lab, University College London, Torrington Place)

Abstract

Prevention and mitigation of thermal runaway presents one of the greatest challenges for the safe operation of lithium-ion batteries. Here, we demonstrate for the first time the application of high-speed synchrotron X-ray computed tomography and radiography, in conjunction with thermal imaging, to track the evolution of internal structural damage and thermal behaviour during initiation and propagation of thermal runaway in lithium-ion batteries. This diagnostic approach is applied to commercial lithium-ion batteries (LG 18650 NMC cells), yielding insights into key degradation modes including gas-induced delamination, electrode layer collapse and propagation of structural degradation. It is envisaged that the use of these techniques will lead to major improvements in the design of Li-ion batteries and their safety features.

Suggested Citation

  • Donal P. Finegan & Mario Scheel & James B. Robinson & Bernhard Tjaden & Ian Hunt & Thomas J. Mason & Jason Millichamp & Marco Di Michiel & Gregory J. Offer & Gareth Hinds & Dan J.L. Brett & Paul R. Sh, 2015. "In-operando high-speed tomography of lithium-ion batteries during thermal runaway," Nature Communications, Nature, vol. 6(1), pages 1-10, November.
    • Handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms7924
    DOI: 10.1038/ncomms7924
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    Cited by:

    1. Xin, Yaoda & Liu, Chenchen & Li, Na & Lyu, Siqi & Song, Wei-Li & Chen, Hao-Sen & Jiao, Shuqiang, 2023. "In-situ monitoring of multiple signals evolution behaviour for commercial lithium-ion batteries during internal short circuit," Applied Energy, Elsevier, vol. 350(C).
    2. Li, Yi & Liu, Kailong & Foley, Aoife M. & Zülke, Alana & Berecibar, Maitane & Nanini-Maury, Elise & Van Mierlo, Joeri & Hoster, Harry E., 2019. "Data-driven health estimation and lifetime prediction of lithium-ion batteries: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    3. Craig, Ben & Schoetz, Theresa & Cruden, Andrew & Ponce de Leon, Carlos, 2020. "Review of current progress in non-aqueous aluminium batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    4. Rémy Richard Jacquemond & Maxime van der Heijden & Emre Burak Boz & Eric Ricardo Carreón Ruiz & Katharine Virginia Greco & Jeffrey Adam Kowalski & Vanesa Muñoz Perales & Fikile Richard Brushett & Kitt, 2024. "Quantifying concentration distributions in redox flow batteries with neutron radiography," Nature Communications, Nature, vol. 15(1), pages 1-16, December.
    5. Huang, Zonghou & Shen, Ting & Jin, Kaiqiang & Sun, Jinhua & Wang, Qingsong, 2022. "Heating power effect on the thermal runaway characteristics of large-format lithium ion battery with Li(Ni1/3Co1/3Mn1/3)O2 as cathode," Energy, Elsevier, vol. 239(PA).
    6. Andreas Ziegler & David Oeser & Thiemo Hein & Daniel Montesinos-Miracle & Ansgar Ackva, 2020. "Run to Failure: Aging of Commercial Battery Cells beyond Their End of Life," Energies, MDPI, vol. 13(8), pages 1-11, April.
    7. Yang, Yang & Yuan, Wei & Zhang, Xiaoqing & Yuan, Yuhang & Wang, Chun & Ye, Yintong & Huang, Yao & Qiu, Zhiqiang & Tang, Yong, 2020. "Overview on the applications of three-dimensional printing for rechargeable lithium-ion batteries," Applied Energy, Elsevier, vol. 257(C).
    8. Yubai Li & Zhifu Zhou & Wei-Tao Wu, 2020. "Three-Dimensional Thermal Modeling of Internal Shorting Process in a 20Ah Lithium-Ion Polymer Battery," Energies, MDPI, vol. 13(4), pages 1-16, February.
    9. Kang, Zhuang & Peng, Qingguo & Yin, Ruixue & Yao, Zhengmin & Song, Yangyang & He, Biao, 2024. "Investigation of multifactorial effects on the thermal performance of battery pack inserted with multi-layer phase change materials," Energy, Elsevier, vol. 290(C).
    10. Xu, Bin & Lee, Jinwoo & Kwon, Daeil & Kong, Lingxi & Pecht, Michael, 2021. "Mitigation strategies for Li-ion battery thermal runaway: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    11. Wang, Haimin & Shi, Weijie & Hu, Feng & Wang, Yufei & Hu, Xuebin & Li, Huanqi, 2021. "Over-heating triggered thermal runaway behavior for lithium-ion battery with high nickel content in positive electrode," Energy, Elsevier, vol. 224(C).
    12. Saurabh Saxena & Yinjiao Xing & Michael Pecht, 2018. "A Unique Failure Mechanism in the Nexus 6P Lithium-Ion Battery," Energies, MDPI, vol. 11(4), pages 1-13, April.
    13. Lingxi Kong & Chuan Li & Jiuchun Jiang & Michael G. Pecht, 2018. "Li-Ion Battery Fire Hazards and Safety Strategies," Energies, MDPI, vol. 11(9), pages 1-11, August.
    14. Ren, Dongsheng & Feng, Xuning & Lu, Languang & He, Xiangming & Ouyang, Minggao, 2019. "Overcharge behaviors and failure mechanism of lithium-ion batteries under different test conditions," Applied Energy, Elsevier, vol. 250(C), pages 323-332.
    15. Feng, Xuning & Zheng, Siqi & Ren, Dongsheng & He, Xiangming & Wang, Li & Cui, Hao & Liu, Xiang & Jin, Changyong & Zhang, Fangshu & Xu, Chengshan & Hsu, Hungjen & Gao, Shang & Chen, Tianyu & Li, Yalun , 2019. "Investigating the thermal runaway mechanisms of lithium-ion batteries based on thermal analysis database," Applied Energy, Elsevier, vol. 246(C), pages 53-64.
    16. Liu, Tong & Tao, Changfa & Wang, Xishi, 2020. "Cooling control effect of water mist on thermal runaway propagation in lithium ion battery modules," Applied Energy, Elsevier, vol. 267(C).
    17. Wei, Gang & Huang, Ranjun & Zhang, Guangxu & Jiang, Bo & Zhu, Jiangong & Guo, Yangyang & Han, Guangshuai & Wei, Xuezhe & Dai, Haifeng, 2023. "A comprehensive insight into the thermal runaway issues in the view of lithium-ion battery intrinsic safety performance and venting gas explosion hazards," Applied Energy, Elsevier, vol. 349(C).
    18. Hossain, Eklas & Roy, Shidhartho & Mohammad, Naeem & Nawar, Nafiu & Dipta, Debopriya Roy, 2021. "Metrics and enhancement strategies for grid resilience and reliability during natural disasters," Applied Energy, Elsevier, vol. 290(C).
    19. Plunkett, Samuel T. & Chen, Chengxiu & Rojaee, Ramin & Doherty, Patrick & Sik Oh, Yun & Galazutdinova, Yana & Krishnamurthy, Mahesh & Al-Hallaj, Said, 2021. "Enhancing thermal safety in lithium-ion battery packs through parallel cell ‘current dumping’ mitigation," Applied Energy, Elsevier, vol. 286(C).
    20. Fransson, Matilda & Broche, Ludovic & Reid, Hamish T. & Patel, Drasti & Rack, Alexander & Shearing, Paul R., 2024. "Investigating thermal runaway dynamics and integrated safety mechanisms of micro-batteries using high-speed X-ray imaging," Applied Energy, Elsevier, vol. 369(C).
    21. Li, Yalun & Gao, Xinlei & Feng, Xuning & Ren, Dongsheng & Li, Yan & Hou, Junxian & Wu, Yu & Du, Jiuyu & Lu, Languang & Ouyang, Minggao, 2022. "Battery eruption triggered by plated lithium on an anode during thermal runaway after fast charging," Energy, Elsevier, vol. 239(PB).
    22. Yi Wu & Saurabh Saxena & Yinjiao Xing & Youren Wang & Chuan Li & Winco K. C. Yung & Michael Pecht, 2018. "Analysis of Manufacturing-Induced Defects and Structural Deformations in Lithium-Ion Batteries Using Computed Tomography," Energies, MDPI, vol. 11(4), pages 1-22, April.
    23. Huang, Peifeng & Ping, Ping & Li, Ke & Chen, Haodong & Wang, Qingsong & Wen, Jennifer & Sun, Jinhua, 2016. "Experimental and modeling analysis of thermal runaway propagation over the large format energy storage battery module with Li4Ti5O12 anode," Applied Energy, Elsevier, vol. 183(C), pages 659-673.

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