IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v5y2014i1d10.1038_ncomms6050.html
   My bibliography  Save this article

Enantioselective synthesis of helical polydiacetylene by application of linearly polarized light and magnetic field

Author

Listed:
  • Yangyang Xu

    (CAS Key Laboratory of Soft Matter Chemistry, Key Laboratory of Optoelectronic Science and Technology in Anhui Province, University of Science and Technology of China, Hefei)

  • Guang Yang

    (CAS Key Laboratory of Soft Matter Chemistry, Key Laboratory of Optoelectronic Science and Technology in Anhui Province, University of Science and Technology of China, Hefei)

  • Hongyan Xia

    (CAS Key Laboratory of Soft Matter Chemistry, Key Laboratory of Optoelectronic Science and Technology in Anhui Province, University of Science and Technology of China, Hefei)

  • Gang Zou

    (CAS Key Laboratory of Soft Matter Chemistry, Key Laboratory of Optoelectronic Science and Technology in Anhui Province, University of Science and Technology of China, Hefei)

  • Qijin Zhang

    (CAS Key Laboratory of Soft Matter Chemistry, Key Laboratory of Optoelectronic Science and Technology in Anhui Province, University of Science and Technology of China, Hefei)

  • Jiangang Gao

    (School of Biological and Chemical Engineering, Anhui Polytechnic University, Wuhu)

Abstract

Magnetic optical activity, which can occur in all media and is induced by longitudinal magnetic field, causes the difference in absorption coefficients of left and right circularly polarized light and has the potential for magnetically induced enantioselectivity in chemical reactions. Compared with the well-established technique with circularly polarized light, there are few reports on the production of helical conjugated polymers in a photochemical reaction based on above magnetochiral anisotropy mechanism. Herein, we demonstrate experimentally that the enantioselective polymerization of diacetylene derivative can be achieved in the liquid crystal phase by application of linearly polarized light under a parallel or antiparallel magnetic field. The screw direction of predominant helical polydiacetylene chain can be rigorously controlled with the relative orientation of linearly polarized light and the magnetic field. Moreover, the prepared helical polydiacetylene assemblies can serve as a direct visual probe for the enantioselective recognition of D- or L-lysine.

Suggested Citation

  • Yangyang Xu & Guang Yang & Hongyan Xia & Gang Zou & Qijin Zhang & Jiangang Gao, 2014. "Enantioselective synthesis of helical polydiacetylene by application of linearly polarized light and magnetic field," Nature Communications, Nature, vol. 5(1), pages 1-6, December.
  • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6050
    DOI: 10.1038/ncomms6050
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/ncomms6050
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/ncomms6050?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yajie Zhou & Yaxin Wang & Yonghui Song & Shanshan Zhao & Mingjiang Zhang & Guangen Li & Qi Guo & Zhi Tong & Zeyi Li & Shan Jin & Hong-Bin Yao & Manzhou Zhu & Taotao Zhuang, 2024. "Helical-caging enables single-emitted large asymmetric full-color circularly polarized luminescence," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6050. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.