IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v16y2025i1d10.1038_s41467-025-58813-3.html
   My bibliography  Save this article

Pulsed electrosynthesis of glycolic acid through polyethylene terephthalate upcycling over a mesoporous PdCu catalyst

Author

Listed:
  • Shu Han

    (Sichuan University)

  • Lizhi Sun

    (Sichuan University)

  • Dongping Fan

    (Sichuan University)

  • Ben Liu

    (Sichuan University)

Abstract

Electrocatalytic upcycling of polyethylene terephthalate (PET) plastics offers a promising and sustainable route that not only addresses serious waste pollution but also produces high value-added chemicals. Despite some important achievements, their activity and selectivity have been slower than needed. In this work, pulsed electrocatalysis is employed to engineer chemisorption properties on a lamellar mesoporous PdCu (LM-PdCu) catalyst, which delivers high activity and stability for selective electrosynthesis of high value-added glycolic acid (GA) from PET upcycling under ambient conditions. LM-PdCu is synthesized by in situ nucleation and attachment strategy along assembled lamellar templates, whose stacked morphology and lamellar mesoporous structure kinetically accelerate selective desorption of GA and expose fresh active sites of metal catalysts for continuous electrocatalysis at pulsed mode. This strategy thus delivers GA Faraday efficiency of >92% in wide potential windows, yield rate of reaching 0.475 mmol cm–2 h–1, and cycling stability of exceeding 20 cycles for electrocatalytic PET upcycling. Moreover, pulsed electrocatalysis discloses good electrocatalytic performance for scaled-up GA electrosynthesis from real bottle waste plastics. This work presents a sustainable route for selective electrosynthesis of value-added chemicals through upcycling of various waste feedstocks.

Suggested Citation

  • Shu Han & Lizhi Sun & Dongping Fan & Ben Liu, 2025. "Pulsed electrosynthesis of glycolic acid through polyethylene terephthalate upcycling over a mesoporous PdCu catalyst," Nature Communications, Nature, vol. 16(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-58813-3
    DOI: 10.1038/s41467-025-58813-3
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-025-58813-3
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-025-58813-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-58813-3. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.