IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-51385-8.html
   My bibliography  Save this article

Combining electron transfer, spin crossover, and redox properties in metal-organic frameworks

Author

Listed:
  • Livia Getzner

    (INP)

  • Damian Paliwoda

    (INP)

  • Laure Vendier

    (INP)

  • Latévi Max Lawson-Daku

    (CH-1211 Genève 4)

  • Aurelian Rotaru

    (Stefan cel Mare University of Suceava)

  • Gábor Molnár

    (INP)

  • Saioa Cobo

    (INP)

  • Azzedine Bousseksou

    (INP)

Abstract

Hofmann coordination polymers (CPs) that couple the well-studied spin transition of the FeII central ion with electron-responsive ligands provide an innovative strategy toward multifunctional metal-organic frameworks (MOFs). Here, we developed a 2D planar network consisting of metal-cyanide-metal sheets in an unusual coordination mode, brought about by infinitely π-stacked redox-active bipyridinium derivatives as axial ligands. The obtained family of materials show vivid thermochromism attributed to electron transfer and/or electronic spin state change processes that can occur either independently or concomitantly. Importantly, the redox activity of the ligands within the structure leads to the quasi-reversible electrochemical reduction reaction on a spin-crossover complex at solid state. These observations have been confirmed via temperature-dependent single-crystal X-ray diffraction, magnetic measurements, Mössbauer, EPR, optical and vibrational spectroscopies as well as quantum chemical calculations.

Suggested Citation

  • Livia Getzner & Damian Paliwoda & Laure Vendier & Latévi Max Lawson-Daku & Aurelian Rotaru & Gábor Molnár & Saioa Cobo & Azzedine Bousseksou, 2024. "Combining electron transfer, spin crossover, and redox properties in metal-organic frameworks," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51385-8
    DOI: 10.1038/s41467-024-51385-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-51385-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-51385-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Ji-Xiang Hu & Qi Li & Hai-Lang Zhu & Zhen-Ni Gao & Qian Zhang & Tao Liu & Guo-Ming Wang, 2022. "Achieving large thermal hysteresis in an anthracene-based manganese(II) complex via photo-induced electron transfer," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Xiao-Qing Yu & Cai Sun & Bin-Wen Liu & Ming-Sheng Wang & Guo-Cong Guo, 2020. "Directed self-assembly of viologen-based 2D semiconductors with intrinsic UV–SWIR photoresponse after photo/thermo activation," Nature Communications, Nature, vol. 11(1), pages 1-7, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ji-Xiang Hu & Qi Li & Hai-Lang Zhu & Zhen-Ni Gao & Qian Zhang & Tao Liu & Guo-Ming Wang, 2022. "Achieving large thermal hysteresis in an anthracene-based manganese(II) complex via photo-induced electron transfer," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51385-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.