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A dodecamethoxy[6]cycloparaphenylene consisting entirely of hydroquinone ethers: unveiling in-plane aromaticity through a rotaxane structure

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  • Naoki Narita

    (Tokyo University of Science)

  • Yusuke Kurita

    (Tokyo University of Science)

  • Kohtaro Osakada

    (Institute of Innovative Research, Tokyo Institute of Technology)

  • Tomohito Ide

    (National Institute of Technology, Tokyo College)

  • Hidetoshi Kawai

    (Tokyo University of Science)

  • Yoshitaka Tsuchido

    (Tokyo University of Science)

Abstract

[n]Cycloparaphenylenes ([n]CPPs, where n is the number of phenylene groups), consisting of 1,4-linked phenylene unit, have attracted much attention due to their cyclic π-conjugated structures and physical properties. However, functionalizing of the benzene rings of smaller [n]CPPs (n

Suggested Citation

  • Naoki Narita & Yusuke Kurita & Kohtaro Osakada & Tomohito Ide & Hidetoshi Kawai & Yoshitaka Tsuchido, 2023. "A dodecamethoxy[6]cycloparaphenylene consisting entirely of hydroquinone ethers: unveiling in-plane aromaticity through a rotaxane structure," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-43907-7
    DOI: 10.1038/s41467-023-43907-7
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    References listed on IDEAS

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    1. Martin D. Peeks & Timothy D. W. Claridge & Harry L. Anderson, 2017. "Aromatic and antiaromatic ring currents in a molecular nanoring," Nature, Nature, vol. 541(7636), pages 200-203, January.
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