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Organic‒inorganic semi-interpenetrating networks with orthogonal light- and magnetic-responsiveness for smart photonic gels

Author

Listed:
  • Minghao Wang

    (University of Science and Technology of China)

  • Chen Nie

    (University of Science and Technology of China)

  • Junbang Liu

    (University of Science and Technology of China)

  • Si Wu

    (University of Science and Technology of China)

Abstract

Living matter has the ability to perceive multiple stimuli and respond accordingly. However, the integration of multiple stimuli-responsiveness in artificial materials usually causes mutual interference, which makes artificial materials work improperly. Herein, we design composite gels with organic‒inorganic semi-interpenetrating network structures, which are orthogonally responsive to light and magnetic fields. The composite gels are prepared by the co-assembly of a photoswitchable organogelator (Azo-Ch) and superparamagnetic inorganic nanoparticles (Fe3O4@SiO2). Azo-Ch assembles into an organogel network, which shows photoinduced reversible sol-gel transitions. In gel or sol state, Fe3O4@SiO2 nanoparticles reversibly form photonic nanochains via magnetic control. Light and magnetic fields can orthogonally control the composite gel because Azo-Ch and Fe3O4@SiO2 form a unique semi-interpenetrating network, which allows them to work independently. The orthogonal photo- and magnetic-responsiveness enables the fabrication of smart windows, anti-counterfeiting labels, and reconfigurable materials using the composite gel. Our work presents a method to design orthogonally stimuli-responsive materials.

Suggested Citation

  • Minghao Wang & Chen Nie & Junbang Liu & Si Wu, 2023. "Organic‒inorganic semi-interpenetrating networks with orthogonal light- and magnetic-responsiveness for smart photonic gels," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36706-7
    DOI: 10.1038/s41467-023-36706-7
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    References listed on IDEAS

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    1. Minghui Tan & Pan Tian & Qian Zhang & Guiqiang Zhu & Yuchen Liu & Mengjiao Cheng & Feng Shi, 2022. "Self-sorting in macroscopic supramolecular self-assembly via additive effects of capillary and magnetic forces," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Yao-Yu Xiao & Zhi-Chao Jiang & Jun-Bo Hou & Yue Zhao, 2021. "Desynchronized liquid crystalline network actuators with deformation reversal capability," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
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