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Near-critical spreading of droplets

Author

Listed:
  • Raphael Saiseau

    (UMR 5798
    Université Paris Cité)

  • Christian Pedersen

    (University of Oslo)

  • Anwar Benjana

    (UMR 5798)

  • Andreas Carlson

    (University of Oslo)

  • Ulysse Delabre

    (UMR 5798)

  • Thomas Salez

    (UMR 5798)

  • Jean-Pierre Delville

    (UMR 5798)

Abstract

We study the spreading of droplets in a near-critical phase-separated liquid mixture, using a combination of experiments, lubrication theory and finite-element numerical simulations. The classical Tanner’s law describing the spreading of viscous droplets is robustly verified when the critical temperature is neared. Furthermore, the microscopic cut-off length scale emerging in this law is obtained as a single free parameter for each given temperature. In total-wetting conditions, this length is interpreted as the thickness of the thin precursor film present ahead of the apparent contact line. The collapse of the different evolutions onto a single Tanner-like master curve demonstrates the universality of viscous spreading before entering in the fluctuation-dominated regime. Finally, our results reveal a counter-intuitive and sharp thinning of the precursor film when approaching the critical temperature, which is attributed to the vanishing spreading parameter at the critical point.

Suggested Citation

  • Raphael Saiseau & Christian Pedersen & Anwar Benjana & Andreas Carlson & Ulysse Delabre & Thomas Salez & Jean-Pierre Delville, 2022. "Near-critical spreading of droplets," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35047-1
    DOI: 10.1038/s41467-022-35047-1
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