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Size-matched hydrogen bonded hydroxylammonium frameworks for regulation of energetic materials

Author

Listed:
  • Qi Lai

    (Beijing Institute of Technology
    University of Idaho
    Beijing Institute of Technology Chongqing Innovation Center)

  • Le Pei

    (Beijing Institute of Technology
    University of Idaho
    Beijing Institute of Technology Chongqing Innovation Center)

  • Teng Fei

    (Beijing Institute of Technology)

  • Ping Yin

    (Beijing Institute of Technology
    University of Idaho
    Beijing Institute of Technology Chongqing Innovation Center)

  • Siping Pang

    (Beijing Institute of Technology)

  • Jean’ne M. Shreeve

    (University of Idaho)

Abstract

Size matching molecular design utilizing host-guest chemistry is a general, promising strategy for seeking new functional materials. With the growing trend of multidisciplinary investigations, taming the metastable high-energy guest moiety in well-matched frameworks is a new pathway leading to innovative energetic materials. Presented is a selective encapsulation in hydrogen-bonded hydroxylammonium frameworks (HHF) by screening different sized nitrogen-rich azoles. The size-match between a sensitive high-energy guest and an HHF not only gives rise to higher energetic performance by dense packing, but also reinforces the layer-by-layer structure which can stabilize the resulting materials towards external mechanic stimuli. Preliminary assessment based on calculated detonation properties and mechanical sensitivity indicates that HHF competed well with the energetic performance and molecular stability (detonation velocity = 9286 m s−1, impact sensitivity = 50 J). This work highlights the size-matched phenomenon of HHF and may serve as an alternative strategy for exploring next generation advanced energetic materials.

Suggested Citation

  • Qi Lai & Le Pei & Teng Fei & Ping Yin & Siping Pang & Jean’ne M. Shreeve, 2022. "Size-matched hydrogen bonded hydroxylammonium frameworks for regulation of energetic materials," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34686-8
    DOI: 10.1038/s41467-022-34686-8
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    References listed on IDEAS

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    1. Alexandra Witze, 2013. "Green fuels blast off," Nature, Nature, vol. 500(7464), pages 509-510, August.
    2. Jichuan Zhang & Yongan Feng & Richard J. Staples & Jiaheng Zhang & Jean’ne M. Shreeve, 2021. "Taming nitroformate through encapsulation with nitrogen-rich hydrogen-bonded organic frameworks," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    3. Serge Desgreniers, 2020. "A milestone in the hunt for metallic hydrogen," Nature, Nature, vol. 577(7792), pages 626-627, January.
    4. Elizabeth Gibney & Richard Van Noorden & Heidi Ledford & Davide Castelvecchi & Matthew Warren, 2018. "‘Test-tube’ evolution wins Chemistry Nobel Prize," Nature, Nature, vol. 562(7726), pages 176-176, October.
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