IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-33616-y.html
   My bibliography  Save this article

Structural diversity in three-dimensional self-assembly of nanoplatelets by spherical confinement

Author

Listed:
  • Da Wang

    (Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University
    Electron Microscopy for Materials Science (EMAT), University of Antwerp)

  • Michiel Hermes

    (Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University)

  • Stan Najmr

    (University of Pennsylvania)

  • Nikos Tasios

    (Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University)

  • Albert Grau-Carbonell

    (Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University)

  • Yang Liu

    (Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University
    Utrecht University
    Monash Centre for Electron Microscopy, Monash University)

  • Sara Bals

    (Electron Microscopy for Materials Science (EMAT), University of Antwerp)

  • Marjolein Dijkstra

    (Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University)

  • Christopher B. Murray

    (University of Pennsylvania
    University of Pennsylvania)

  • Alfons Blaaderen

    (Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University)

Abstract

Nanoplatelets offer many possibilities to construct advanced materials due to new properties associated with their (semi)two-dimensional shapes. However, precise control of both positional and orientational order of the nanoplatelets in three dimensions, which is required to achieve emerging and collective properties, is challenging to realize. Here, we combine experiments, advanced electron tomography and computer simulations to explore the structure of supraparticles self-assembled from nanoplatelets in slowly drying emulsion droplets. We demonstrate that the rich phase behaviour of nanoplatelets, and its sensitivity to subtle changes in shape and interaction potential can be used to guide the self-assembly into a wide range of different structures, offering precise control over both orientation and position order of the nanoplatelets. Our research is expected to shed light on the design of hierarchically structured metamaterials with distinct shape- and orientation- dependent properties.

Suggested Citation

  • Da Wang & Michiel Hermes & Stan Najmr & Nikos Tasios & Albert Grau-Carbonell & Yang Liu & Sara Bals & Marjolein Dijkstra & Christopher B. Murray & Alfons Blaaderen, 2022. "Structural diversity in three-dimensional self-assembly of nanoplatelets by spherical confinement," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33616-y
    DOI: 10.1038/s41467-022-33616-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-33616-y
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-022-33616-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Angang Dong & Jun Chen & Patrick M. Vora & James M. Kikkawa & Christopher B. Murray, 2010. "Binary nanocrystal superlattice membranes self-assembled at the liquid–air interface," Nature, Nature, vol. 466(7305), pages 474-477, July.
    2. Da Wang & Ernest B. Wee & Daniele Zanaga & Thomas Altantzis & Yaoting Wu & Tonnishtha Dasgupta & Marjolein Dijkstra & Christopher B. Murray & Sara Bals & Alfons Blaaderen, 2021. "Quantitative 3D real-space analysis of Laves phase supraparticles," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    3. Mingyang Wei & F. Pelayo García Arquer & Grant Walters & Zhenyu Yang & Li Na Quan & Younghoon Kim & Randy Sabatini & Rafael Quintero-Bermudez & Liang Gao & James Z. Fan & Fengjia Fan & Aryeh Gold-Park, 2019. "Ultrafast narrowband exciton routing within layered perovskite nanoplatelets enables low-loss luminescent solar concentrators," Nature Energy, Nature, vol. 4(3), pages 197-205, March.
    4. Junwei Wang & Chrameh Fru Mbah & Thomas Przybilla & Benjamin Apeleo Zubiri & Erdmann Spiecker & Michael Engel & Nicolas Vogel, 2018. "Magic number colloidal clusters as minimum free energy structures," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    5. Da Wang & Michiel Hermes & Ramakrishna Kotni & Yaoting Wu & Nikos Tasios & Yang Liu & Bart de Nijs & Ernest B. van der Wee & Christopher B. Murray & Marjolein Dijkstra & Alfons van Blaaderen, 2018. "Interplay between spherical confinement and particle shape on the self-assembly of rounded cubes," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yufei Wang & Yilong Zhou & Quanpeng Yang & Rourav Basak & Yu Xie & Dong Le & Alexander D. Fuqua & Wade Shipley & Zachary Yam & Alex Frano & Gaurav Arya & Andrea R. Tao, 2024. "Self-assembly of nanocrystal checkerboard patterns via non-specific interactions," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Zhihua Cheng & Matthew R. Jones, 2022. "Assembly of planar chiral superlattices from achiral building blocks," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Chrameh Fru Mbah & Junwei Wang & Silvan Englisch & Praveen Bommineni & Nydia Roxana Varela-Rosales & Erdmann Spiecker & Nicolas Vogel & Michael Engel, 2023. "Early-stage bifurcation of crystallization in a sphere," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Yilong Zhou & Gaurav Arya, 2022. "Discovery of two-dimensional binary nanoparticle superlattices using global Monte Carlo optimization," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    5. Daniel Arenas Esteban & Da Wang & Ajinkya Kadu & Noa Olluyn & Ana Sánchez-Iglesias & Alejandro Gomez-Perez & Jesús González-Casablanca & Stavros Nicolopoulos & Luis M. Liz-Marzán & Sara Bals, 2024. "Quantitative 3D structural analysis of small colloidal assemblies under native conditions by liquid-cell fast electron tomography," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    6. Bowen Sui & Youliang Zhu & Xuemei Jiang & Yifan Wang & Niboqia Zhang & Zhongyuan Lu & Bai Yang & Yunfeng Li, 2023. "Recastable assemblies of carbon dots into mechanically robust macroscopic materials," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    7. Richard M. Parker & Tianheng H. Zhao & Bruno Frka-Petesic & Silvia Vignolini, 2022. "Cellulose photonic pigments," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    8. Sangmin Lee & Sharon C. Glotzer, 2022. "Entropically engineered formation of fivefold and icosahedral twinned clusters of colloidal shapes," Nature Communications, Nature, vol. 13(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33616-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.