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Identification and characterization of a new ensemble of cometary organic molecules

Author

Listed:
  • N. Hänni

    (University of Bern)

  • K. Altwegg

    (University of Bern)

  • M. Combi

    (University of Michigan)

  • S. A. Fuselier

    (Space Science Directorate, Southwest Research Institute
    The University of Texas at San Antonio)

  • J. De Keyser

    (Royal Belgian Institute for Space Aeronomy, BIRA-IASB)

  • M. Rubin

    (University of Bern)

  • S. F. Wampfler

    (University of Bern)

Abstract

In-situ study of comet 1P/Halley during its 1986 apparition revealed a surprising abundance of organic coma species. It remained unclear, whether or not these species originated from polymeric matter. Now, high-resolution mass-spectrometric data collected at comet 67P/Churyumov-Gerasimenko by ESA’s Rosetta mission unveil the chemical structure of complex cometary organics. Here, we identify an ensemble of individual molecules with masses up to 140 Da while demonstrating inconsistency of the data with relevant amounts of polymeric matter. The ensemble has an average composition of C1H1.56O0.134N0.046S0.017, identical to meteoritic soluble organic matter, and includes a plethora of chain-based, cyclic, and aromatic hydrocarbons at an approximate ratio of 6:3:1. Its compositional and structural properties, except for the H/C ratio, resemble those of other Solar System reservoirs of organics—from organic material in the Saturnian ring rain to meteoritic soluble and insoluble organic matter –, which is compatible with a shared prestellar history.

Suggested Citation

  • N. Hänni & K. Altwegg & M. Combi & S. A. Fuselier & J. De Keyser & M. Rubin & S. F. Wampfler, 2022. "Identification and characterization of a new ensemble of cometary organic molecules," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31346-9
    DOI: 10.1038/s41467-022-31346-9
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    References listed on IDEAS

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    1. Nicolas Fray & Anaïs Bardyn & Hervé Cottin & Kathrin Altwegg & Donia Baklouti & Christelle Briois & Luigi Colangeli & Cécile Engrand & Henning Fischer & Albrecht Glasmachers & Eberhard Grün & Gerhard , 2016. "High-molecular-weight organic matter in the particles of comet 67P/Churyumov–Gerasimenko," Nature, Nature, vol. 538(7623), pages 72-74, October.
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