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Biomimetic non-classical crystallization drives hierarchical structuring of efficient circularly polarized phosphors

Author

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  • Li-Zhe Feng

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Jing-Jing Wang

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Tao Ma

    (University of Science and Technology of China)

  • Yi-Chen Yin

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Kuang-Hui Song

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Zi-Du Li

    (University of Science and Technology of China
    University of Science and Technology of China
    University of Science and Technology of China)

  • Man-Man Zhou

    (Anhui University, Ministry of Education)

  • Shan Jin

    (Anhui University, Ministry of Education)

  • Taotao Zhuang

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Feng-Jia Fan

    (University of Science and Technology of China
    University of Science and Technology of China
    University of Science and Technology of China)

  • Man-Zhou Zhu

    (Anhui University, Ministry of Education)

  • Hong-Bin Yao

    (University of Science and Technology of China
    University of Science and Technology of China)

Abstract

Hierarchically structured chiral luminescent materials hold promise for achieving efficient circularly polarized luminescence. However, a feasible chemical route to fabricate hierarchically structured chiral luminescent polycrystals is still elusive because of their complex structures and complicated formation process. We here report a biomimetic non-classical crystallization (BNCC) strategy for preparing efficient hierarchically structured chiral luminescent polycrystals using well-designed highly luminescent homochiral copper(I)-iodide hybrid clusters as basic units for non-classical crystallization. By monitoring the crystallization process, we unravel the BNCC mechanism, which involves crystal nucleation, nanoparticles aggregation, oriented attachment, and mesoscopic transformation processes. We finally obtain the circularly polarized phosphors with both high luminescent efficiency of 32% and high luminescent dissymmetry factor of 1.5 × 10−2, achieving the demonstration of a circularly polarized phosphor converted light emitting diode with a polarization degree of 1.84% at room temperature. Our designed BNCC strategy provides a simple, reliable, and large-scale synthetic route for preparing bright circularly polarized phosphors.

Suggested Citation

  • Li-Zhe Feng & Jing-Jing Wang & Tao Ma & Yi-Chen Yin & Kuang-Hui Song & Zi-Du Li & Man-Man Zhou & Shan Jin & Taotao Zhuang & Feng-Jia Fan & Man-Zhou Zhu & Hong-Bin Yao, 2022. "Biomimetic non-classical crystallization drives hierarchical structuring of efficient circularly polarized phosphors," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30989-y
    DOI: 10.1038/s41467-022-30989-y
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    1. Jacob F. Sherson & Hanna Krauter & Rasmus K. Olsson & Brian Julsgaard & Klemens Hammerer & Ignacio Cirac & Eugene S. Polzik, 2006. "Quantum teleportation between light and matter," Nature, Nature, vol. 443(7111), pages 557-560, October.
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    1. Xiao-Hong Ma & Jing Li & Peng Luo & Jia-Hua Hu & Zhen Han & Xi-Yan Dong & Guohua Xie & Shuang-Quan Zang, 2023. "Carbene-stabilized enantiopure heterometallic clusters featuring EQE of 20.8% in circularly-polarized OLED," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

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