IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-29222-7.html
   My bibliography  Save this article

New black indium oxide—tandem photothermal CO2-H2 methanol selective catalyst

Author

Listed:
  • Zeshu Zhang

    (The Chinese University of Hong Kong, Shenzhen)

  • Chengliang Mao

    (University of Toronto
    Central China Normal University)

  • Débora Motta Meira

    (Argonne National Laboratory
    Canadian Light Source Inc.)

  • Paul N. Duchesne

    (Queen’s University)

  • Athanasios A. Tountas

    (University of Toronto)

  • Zhao Li

    (University of Toronto)

  • Chenyue Qiu

    (University of Toronto)

  • Sanli Tang

    (University of Toronto)

  • Rui Song

    (University of Toronto)

  • Xue Ding

    (The Chinese University of Hong Kong, Shenzhen)

  • Junchuan Sun

    (The Chinese University of Hong Kong, Shenzhen)

  • Jiangfan Yu

    (The Chinese University of Hong Kong, Shenzhen)

  • Jane Y. Howe

    (University of Toronto
    University of Toronto)

  • Wenguang Tu

    (The Chinese University of Hong Kong, Shenzhen)

  • Lu Wang

    (The Chinese University of Hong Kong, Shenzhen)

  • Geoffrey A. Ozin

    (University of Toronto)

Abstract

It has long been known that the thermal catalyst Cu/ZnO/Al2O3(CZA) can enable remarkable catalytic performance towards CO2 hydrogenation for the reverse water-gas shift (RWGS) and methanol synthesis reactions. However, owing to the direct competition between these reactions, high pressure and high hydrogen concentration (≥75%) are required to shift the thermodynamic equilibrium towards methanol synthesis. Herein, a new black indium oxide with photothermal catalytic activity is successfully prepared, and it facilitates a tandem synthesis of methanol at a low hydrogen concentration (50%) and ambient pressure by directly using by-product CO as feedstock. The methanol selectivities achieve 33.24% and 49.23% at low and high hydrogen concentrations, respectively.

Suggested Citation

  • Zeshu Zhang & Chengliang Mao & Débora Motta Meira & Paul N. Duchesne & Athanasios A. Tountas & Zhao Li & Chenyue Qiu & Sanli Tang & Rui Song & Xue Ding & Junchuan Sun & Jiangfan Yu & Jane Y. Howe & We, 2022. "New black indium oxide—tandem photothermal CO2-H2 methanol selective catalyst," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29222-7
    DOI: 10.1038/s41467-022-29222-7
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-29222-7
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-022-29222-7?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Bingqiao Xie & Roong Jien Wong & Tze Hao Tan & Michael Higham & Emma K. Gibson & Donato Decarolis & June Callison & Kondo-Francois Aguey-Zinsou & Michael Bowker & C. Richard A. Catlow & Jason Scott & , 2020. "Synergistic ultraviolet and visible light photo-activation enables intensified low-temperature methanol synthesis over copper/zinc oxide/alumina," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    2. Yiou Wang & Xu Liu & Xiaoyu Han & Robert Godin & Jialu Chen & Wuzong Zhou & Chaoran Jiang & Jamie F. Thompson & K. Bayazit Mustafa & Stephen A. Shevlin & James R. Durrant & Zhengxiao Guo & Junwang Tan, 2020. "Unique hole-accepting carbon-dots promoting selective carbon dioxide reduction nearly 100% to methanol by pure water," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    3. Lu Wang & Yuchan Dong & Tingjiang Yan & Zhixin Hu & Feysal M. Ali & Débora Motta Meira & Paul N. Duchesne & Joel Yi Yang Loh & Chenyue Qiu & Emily E. Storey & Yangfan Xu & Wei Sun & Mireille Ghoussoub, 2020. "Black indium oxide a photothermal CO2 hydrogenation catalyst," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xiaoqing Yan & Mengyang Xia & Hanxuan Liu & Bin Zhang & Chunran Chang & Lianzhou Wang & Guidong Yang, 2023. "An electron-hole rich dual-site nickel catalyst for efficient photocatalytic overall water splitting," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Yang Liu & Jianhui Sun & Houhou Huang & Linlu Bai & Xiaomeng Zhao & Binhong Qu & Lunqiao Xiong & Fuquan Bai & Junwang Tang & Liqiang Jing, 2023. "Improving CO2 photoconversion with ionic liquid and Co single atoms," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Lu, Buchu & Yan, Xiangyu & Liu, Qibin, 2023. "Enhanced solar hydrogen generation with the direct coupling of photo and thermal energy – An experimental and mechanism study," Applied Energy, Elsevier, vol. 331(C).
    4. Lei Luo & Lei Fu & Huifen Liu & Youxun Xu & Jialiang Xing & Chun-Ran Chang & Dong-Yuan Yang & Junwang Tang, 2022. "Synergy of Pd atoms and oxygen vacancies on In2O3 for methane conversion under visible light," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    5. Yifan Gao & Shuai Liang & Biming Liu & Chengxu Jiang & Chenyang Xu & Xiaoyuan Zhang & Peng Liang & Menachem Elimelech & Xia Huang, 2023. "Subtle tuning of nanodefects actuates highly efficient electrocatalytic oxidation," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    6. Yaguang Li & Xianhua Bai & Dachao Yuan & Fengyu Zhang & Bo Li & Xingyuan San & Baolai Liang & Shufang Wang & Jun Luo & Guangsheng Fu, 2022. "General heterostructure strategy of photothermal materials for scalable solar-heating hydrogen production without the consumption of artificial energy," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. He, He & Chen, Huayu & Ning, Pei & Liang, Junhui & Yao, Xin & Gao, Yanfang & Byambatsogt, Pashka & Qin, Laishun & Huang, Yuexiang & Chen, Da, 2022. "Boosting photocatalytic hydrogen evolution over 2D/0D graphene/H–In2O3 nanohybrids with regulated oxygen vacancies," Renewable Energy, Elsevier, vol. 194(C), pages 868-874.
    8. Xueying Wan & Yifan Li & Yihong Chen & Jun Ma & Ying-Ao Liu & En-Dian Zhao & Yadi Gu & Yilin Zhao & Yi Cui & Rongtan Li & Dong Liu & Ran Long & Kim Meow Liew & Yujie Xiong, 2024. "A nonmetallic plasmonic catalyst for photothermal CO2 flow conversion with high activity, selectivity and durability," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    9. Lei Luo & Xiaoyu Han & Keran Wang & Youxun Xu & Lunqiao Xiong & Jiani Ma & Zhengxiao Guo & Junwang Tang, 2023. "Nearly 100% selective and visible-light-driven methane conversion to formaldehyde via. single-atom Cu and Wδ+," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    10. Jijia Xie & Xiyi Li & Jian Guo & Lei Luo & Juan J. Delgado & Natalia Martsinovich & Junwang Tang, 2023. "Highly selective oxidation of benzene to phenol with air at room temperature promoted by water," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29222-7. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.