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Preparative-scale synthesis of nonacene

Author

Listed:
  • Andrej Jančařík

    (GNS Group, CEMES-CNRS
    Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences
    Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, UMR 5031)

  • Jan Holec

    (GNS Group, CEMES-CNRS)

  • Yuuya Nagata

    (Hokkaido University)

  • Michal Šámal

    (Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences)

  • Andre Gourdon

    (GNS Group, CEMES-CNRS)

Abstract

During the last years we have witnessed progressive evolution of preparation of acenes with length up to dodecacene by on-surface synthesis in ultra-high vacuum or generation of acenes up to decacene in solid matrices at low temperatures. While these protocols with very specific conditions produce the acenes in amount of few molecules, the strategies leading to the acenes in large quantities dawdle behind. Only recently and after 70 years of synthetic attempts, heptacene has been prepared in bulk phase. However, the preparative scale synthesis of higher homologues still remains a formidable challenge. Here we report the preparation and characterisation of nonacene and show its excellent thermal and in-time stability.

Suggested Citation

  • Andrej Jančařík & Jan Holec & Yuuya Nagata & Michal Šámal & Andre Gourdon, 2022. "Preparative-scale synthesis of nonacene," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-021-27809-0
    DOI: 10.1038/s41467-021-27809-0
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    References listed on IDEAS

    as
    1. Richard Korytár & Dimitra Xenioti & Peter Schmitteckert & Mébarek Alouani & Ferdinand Evers, 2014. "Signature of the Dirac cone in the properties of linear oligoacenes," Nature Communications, Nature, vol. 5(1), pages 1-7, December.
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    Cited by:

    1. Cheng Chen & Yongkang Guo & Zhidong Chang & Klaus Müllen & Xiao-Ye Wang, 2024. "Synthesis of quadruply boron-doped acenes with stimuli-responsive multicolor emission," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Preeta Pratakshya & Chengyi Xu & David J. Dibble & Aliya Mukazhanova & Panyiming Liu & Anthony M. Burke & Reina Kurakake & Robert Lopez & Philip R. Dennison & Sahar Sharifzadeh & Alon A. Gorodetsky, 2023. "Octopus-inspired deception and signaling systems from an exceptionally-stable acene variant," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

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