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Fast ion transport for synthesis and stabilization of β-Zn4Sb3

Author

Listed:
  • Dongwang Yang

    (Wuhan University of Technology)

  • Xianli Su

    (Wuhan University of Technology)

  • Jian He

    (Clemson University)

  • Yonggao Yan

    (Wuhan University of Technology)

  • Jun Li

    (Wuhan University of Technology)

  • Hui Bai

    (Wuhan University of Technology
    Wuhan University of Technology)

  • Tingting Luo

    (Wuhan University of Technology
    Wuhan University of Technology)

  • Yamei Liu

    (Clemson University)

  • Hao Luo

    (Wuhan University of Technology
    Wuhan University of Technology)

  • Yimeng Yu

    (Wuhan University of Technology
    Wuhan University of Technology)

  • Jinsong Wu

    (Wuhan University of Technology
    Wuhan University of Technology)

  • Qingjie Zhang

    (Wuhan University of Technology)

  • Ctirad Uher

    (University of Michigan)

  • Xinfeng Tang

    (Wuhan University of Technology)

Abstract

Mobile ion-enabled phenomena make β-Zn4Sb3 a promising material in terms of the re-entry phase instability behavior, mixed electronic ionic conduction, and thermoelectric performance. Here, we utilize the fast Zn2+ migration under a sawtooth waveform electric field and a dynamical growth of 3-dimensional ionic conduction network to achieve ultra-fast synthesis of β-Zn4Sb3. Moreover, the interplay between the mobile ions, electric field, and temperature field gives rise to exquisite core-shell crystalline-amorphous microstructures that self-adaptively stabilize β-Zn4Sb3. Doping Cd or Ge on the Zn site as steric hindrance further stabilizes β-Zn4Sb3 by restricting long-range Zn2+ migration and extends the operation temperature range of high thermoelectric performance. These results provide insight into the development of mixed-conduction thermoelectric materials, batteries, and other functional materials.

Suggested Citation

  • Dongwang Yang & Xianli Su & Jian He & Yonggao Yan & Jun Li & Hui Bai & Tingting Luo & Yamei Liu & Hao Luo & Yimeng Yu & Jinsong Wu & Qingjie Zhang & Ctirad Uher & Xinfeng Tang, 2021. "Fast ion transport for synthesis and stabilization of β-Zn4Sb3," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26265-0
    DOI: 10.1038/s41467-021-26265-0
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    References listed on IDEAS

    as
    1. Pengfei Qiu & Matthias T. Agne & Yongying Liu & Yaqin Zhu & Hongyi Chen & Tao Mao & Jiong Yang & Wenqing Zhang & Sossina M. Haile & Wolfgang G. Zeier & Jürgen Janek & Ctirad Uher & Xun Shi & Lidong Ch, 2018. "Suppression of atom motion and metal deposition in mixed ionic electronic conductors," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
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