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Revealing the chirality origin and homochirality crystallization of Ag14 nanocluster at the molecular level

Author

Listed:
  • Xiao-Qian Liang

    (Shandong University)

  • Ying-Zhou Li

    (Qilu University of Technology (Shandong Academy of Science))

  • Zhi Wang

    (Shandong University)

  • Shan-Shan Zhang

    (Shandong University)

  • Yi-Cheng Liu

    (Shandong University)

  • Zhao-Zhen Cao

    (Shandong University)

  • Lei Feng

    (Shandong University)

  • Zhi-Yong Gao

    (Henan Normal University)

  • Qing-Wang Xue

    (Liaocheng University)

  • Chen-Ho Tung

    (Shandong University)

  • Di Sun

    (Shandong University)

Abstract

Although chirality is an ever-present characteristic in biology and some artificial molecules, controlling the chirality and demystifying the chirality origin of complex assemblies remain challenging. Herein, we report two homochiral Ag14 nanoclusters with inherent chirality originated from identical rotation of six square faces on a Ag8 cube driven by intra-cluster π···π stacking interaction between pntp− (Hpntp = p-nitrothiophenol) ligands. The spontaneous resolution of the racemic (SD/rac-Ag14a) to homochiral nanoclusters (SD/L-Ag14 and SD/R-Ag14) can be realized by re-crystallizing SD/rac-Ag14a in acetonitrile, which promotes the homochiral crystallization in solid state by forming C–H···O/N hydrogen bonds with nitro oxygen atoms in pntp− or aromatic hydrogen atoms in dpph (dpph = 1,6-bis(diphenylphosphino)hexane) on Ag14 nanocluster. This work not only provides strategic guidance for the syntheses of chiral silver nanoclusters in an all-achiral environment, but also deciphers the origin of chirality at molecular level by identifying the special effects of intra- and inter-cluster supramolecular interactions.

Suggested Citation

  • Xiao-Qian Liang & Ying-Zhou Li & Zhi Wang & Shan-Shan Zhang & Yi-Cheng Liu & Zhao-Zhen Cao & Lei Feng & Zhi-Yong Gao & Qing-Wang Xue & Chen-Ho Tung & Di Sun, 2021. "Revealing the chirality origin and homochirality crystallization of Ag14 nanocluster at the molecular level," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-25275-2
    DOI: 10.1038/s41467-021-25275-2
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    Cited by:

    1. Zhihe Liu & Hua Tan & Bo Li & Zehua Hu & De-en Jiang & Qiaofeng Yao & Lei Wang & Jianping Xie, 2023. "Ligand effect on switching the rate-determining step of water oxidation in atomically precise metal nanoclusters," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Qing Zhang & Weiqiang Wang & Shuang Zhou & Rui Zhang & Irmgard Bischofberger, 2024. "Flow-induced periodic chiral structures in an achiral nematic liquid crystal," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    3. Xi-Ming Luo & Chun-Hua Gong & Fangfang Pan & Yubing Si & Jia-Wang Yuan & Muhammad Asad & Xi-Yan Dong & Shuang-Quan Zang & Thomas C. W. Mak, 2022. "Small symmetry-breaking triggering large chiroptical responses of Ag70 nanoclusters," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    4. Xue-Jing Zhai & Meng-Yu Luo & Xi-Ming Luo & Xi-Yan Dong & Yubing Si & Chong Zhang & Zhen Han & Runping Han & Shuang-Quan Zang & Thomas C. W. Mak, 2024. "Hierarchical assembly of Ag40 nanowheel ranging from building blocks to diverse superstructure regulation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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