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Rational design of a robust aluminum metal-organic framework for multi-purpose water-sorption-driven heat allocations

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  • Kyung Ho Cho

    (Research Group for Nanocatalyst and Center for Convergent Chemical Process (CCP), Korea Research Institute of Chemical Technology (KRICT))

  • D. Damasceno Borges

    (Institut Charles Gerhardt, Montpellier UMR 5253 CNRS ENSCM UM, Université Montpellier, 34095
    Instituto de Física, Universidade Federal de Uberlândia)

  • U-Hwang Lee

    (Research Group for Nanocatalyst and Center for Convergent Chemical Process (CCP), Korea Research Institute of Chemical Technology (KRICT))

  • Ji Sun Lee

    (Research Group for Nanocatalyst and Center for Convergent Chemical Process (CCP), Korea Research Institute of Chemical Technology (KRICT))

  • Ji Woong Yoon

    (Research Group for Nanocatalyst and Center for Convergent Chemical Process (CCP), Korea Research Institute of Chemical Technology (KRICT))

  • Sung June Cho

    (Chonnam National University)

  • Jaedeuk Park

    (Research Group for Nanocatalyst and Center for Convergent Chemical Process (CCP), Korea Research Institute of Chemical Technology (KRICT))

  • Walter Lombardo

    (Consiglio Nazionale delle Ricerche (CNR), Istituto di Tecnologie Avanzate per l’Energia “Nicola Giordano” (ITAE))

  • Dohyun Moon

    (Beamline Department Pohang Accelerator Laboratory (PAL))

  • Alessio Sapienza

    (Consiglio Nazionale delle Ricerche (CNR), Istituto di Tecnologie Avanzate per l’Energia “Nicola Giordano” (ITAE))

  • Guillaume Maurin

    (Institut Charles Gerhardt, Montpellier UMR 5253 CNRS ENSCM UM, Université Montpellier, 34095)

  • Jong-San Chang

    (Research Group for Nanocatalyst and Center for Convergent Chemical Process (CCP), Korea Research Institute of Chemical Technology (KRICT)
    Sungkyunkwan University)

Abstract

Adsorption-driven heat transfer technology using water as working fluid is a promising eco-friendly strategy to address the exponential increase of global energy demands for cooling and heating purposes. Here we present the water sorption properties of a porous aluminum carboxylate metal-organic framework, [Al(OH)(C6H3NO4)]·nH2O, KMF-1, discovered by a joint computational predictive and experimental approaches, which exhibits step-like sorption isotherms, record volumetric working capacity (0.36 mL mL−1) and specific energy capacity (263 kWh m−3) under cooling working conditions, very high coefficient of performances of 0.75 (cooling) and 1.74 (heating) together with low driving temperature below 70 °C which allows the exploitation of solar heat, high cycling stability and remarkable heat storage capacity (348 kWh m−3). This level of performances makes this porous material as a unique and ideal multi-purpose water adsorbent to tackle the challenges of thermal energy storage and its further efficient exploitation for both cooling and heating applications.

Suggested Citation

  • Kyung Ho Cho & D. Damasceno Borges & U-Hwang Lee & Ji Sun Lee & Ji Woong Yoon & Sung June Cho & Jaedeuk Park & Walter Lombardo & Dohyun Moon & Alessio Sapienza & Guillaume Maurin & Jong-San Chang, 2020. "Rational design of a robust aluminum metal-organic framework for multi-purpose water-sorption-driven heat allocations," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-18968-7
    DOI: 10.1038/s41467-020-18968-7
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    Cited by:

    1. Shahvari, Saba Zakeri & Clark, Jordan D., 2023. "Approaching theoretical maximum energy performance for desiccant dehumidification using staged and optimized metal-organic frameworks," Applied Energy, Elsevier, vol. 331(C).
    2. Enyu Wu & Xiao-Wen Gu & Di Liu & Xu Zhang & Hui Wu & Wei Zhou & Guodong Qian & Bin Li, 2023. "Incorporation of multiple supramolecular binding sites into a robust MOF for benchmark one-step ethylene purification," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Cabeza, Luisa F. & de Gracia, Alvaro & Zsembinszki, Gabriel & Borri, Emiliano, 2021. "Perspectives on thermal energy storage research," Energy, Elsevier, vol. 231(C).
    4. Yinglai Hou & Zhizhi Sheng & Chen Fu & Jie Kong & Xuetong Zhang, 2022. "Hygroscopic holey graphene aerogel fibers enable highly efficient moisture capture, heat allocation and microwave absorption," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    5. Zhou, Yuekuan & Zheng, Siqian & Hensen, Jan L.M., 2024. "Machine learning-based digital district heating/cooling with renewable integrations and advanced low-carbon transition," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).

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