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Connecting glass-forming ability of binary mixtures of soft particles to equilibrium melting temperatures

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  • Yunhuan Nie

    (University of Science and Technology of China)

  • Jun Liu

    (University of Science and Technology of China)

  • Jialing Guo

    (University of Science and Technology of China)

  • Ning Xu

    (University of Science and Technology of China)

Abstract

The glass-forming ability is an important material property for manufacturing glasses and understanding the long-standing glass transition problem. Because of the nonequilibrium nature, it is difficult to develop the theory for it. Here we report that the glass-forming ability of binary mixtures of soft particles is related to the equilibrium melting temperatures. Due to the distinction in particle size or stiffness, the two components in a mixture effectively feel different melting temperatures, leading to a melting temperature gap. By varying the particle size, stiffness, and composition over a wide range of pressures, we establish a comprehensive picture for the glass-forming ability, based on our finding of the direct link between the glass-forming ability and the melting temperature gap. Our study reveals and explains the pressure and interaction dependence of the glass-forming ability of model glass-formers, and suggests strategies to optimize the glass-forming ability via the manipulation of particle interactions.

Suggested Citation

  • Yunhuan Nie & Jun Liu & Jialing Guo & Ning Xu, 2020. "Connecting glass-forming ability of binary mixtures of soft particles to equilibrium melting temperatures," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-16986-z
    DOI: 10.1038/s41467-020-16986-z
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